35420-95-2Relevant articles and documents
ABSORBENT COMPOSITIONS INCLUDING AMINO-SILOXANES
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Paragraph 0064, (2018/11/10)
An absorbent composition including an amino-siloxane is presented. The amino- siloxane includes structure (I): wherein R1 is independently at each occurrence a C1-C6 aliphatic or aromatic radical; R2 is independ
Difluoro- and trifluoro diazoalkanes-complementary approaches in batch and flow and their application in cycloaddition reactions
Hock, Katharina J.,Mertens, Lucas,Metze, Friederike K.,Schmittmann, Clemens,Koenigs, Rene M.
supporting information, p. 905 - 909 (2017/08/14)
Herein we report on applications of fluorinated diazoalkanes in cycloaddition reactions, with the emphasis on studying subtle differences between diverse fluorinated diazo compounds. These differences led to two major synthetic protocols in batch and flow that allow the safe and scalable synthesis of fluoroalkyl-, sulfone-substituted pyrazolines.
Reaction Products and Process of 2-Chloroethyl Ethyl Sulfide in Microemulsion Media
Mei-Ling, Lei,Hai-Ling, Xi,Ming, Shen,Ling, Yuan,Shi-Tong, Han
, p. 387 - 393 (2014/03/21)
The reaction of 2-chloroethyl ethyl sulfide was investigated in several oil-in-water microemulsions. The reaction products were identified by GC/MS, NMR, and LC/MS, and the reaction process was monitored by measuring peak height of reaction products and 2-chloroethyl ethyl sulfide with time by 1H NMR spectroscopy. The result showed that 2-chloroethyl ethyl sulfide degraded to 2-hydroxyethyl ethyl sulfide, cyclic sulfonium ion, open chain sulfonium chloro ion and sulfonium hydroxyl ion, and the reaction proceeded via a cyclic sulfonium ion intermediate. Based on the NMR results, a pseudoternary model was established for the reaction process of 2-chloroethyl ethyl sulfide in microemulsion.