3574-04-7

Basic information

• Product Name: hexamethylcyclotrisilathiane
• Synonyms: hexamethylcyclotrisilathiane
• CAS NO: 3574-04-7
• Molecular Weight: 270.663
• Mol File: 3574-04-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: hexamethylcyclotrisilathiane(CAS DataBase Reference)
• NIST Chemistry Reference: hexamethylcyclotrisilathiane(3574-04-7)
• EPA Substance Registry System: hexamethylcyclotrisilathiane(3574-04-7)

Safety Data

• Hazardous Substances Data: 3574-04-7(Hazardous Substances Data)

Upstream product

• 75-78-5 dimethylsilicon dichloride 
• 182680-28-0 Dimethyl-prop-2-ynylsulfanyl-silane 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 

Downstream Products

• 17937-66-5 bis(benzoyloxy)dimethylsilane 
• 865-36-1 thioformaldehyde 
• 1111-83-7 dimethyl silathione 
• 77205-52-8 3,3-dimethyl-1-thia-3-silacyclobutane 
• 4112-23-6 1-sila-1,1-dimethylethylene 
• 54222-77-4 C₁₆H₁₈N₂O₂Si 
• 617-75-4 triethylarsine 
• 588-59-0 stilbene 
• 466637-53-6 2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate 
• 1870-69-5 triphenyl borthiine 
• 75-78-5 dimethylsilicon dichloride 
• 379262-18-7 Ni(SSiMe₃)2(1,2-diphenylphosphino)ethane) 
• 165334-37-2 2,3-dimethyl-3-triphenylphosphonio-2-silabutane-2-thiolate 
• 126651-22-7 benzyl-t-BuMe₂Si-sulfide 

Relevant articles and documents

Synthesis by FVT and characterization of unhindered silanethiones

The retro-ene reaction of allylthio- and propargylthiosilanes led, under flash vacuum thermolysis (FVT) conditions, to unhindered silanethiones, characterized by their derivatives, and also directly by coupling of the FVT with gas-phase spectrometries. Monomeric silicon oxysulfide has been generated similarly. The unsubstituted silanethione was not obtained, but dehydrogenated into silicon monosulfide during FVT.

Silathione (Me2Si=S) Extrusion in the Thermolysis of Silylthioketenes

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METALLA IV-b-PHOSPHOLANNES II-METALLA-2 (OXA-, THIA- ou AZA-)-3 PHOSPHOLANNES

2-sila-, germa- or stanna- 3-(oxa-, thia- or aza-) phospholanes have been synthesized by reactions of dihalometalla-IV-b compounds with dilithiated β-phosphorus alcohols, thiols or amines HYCH2CH2P(H)Ph (Y=O, S, NMe).Germa- and stanna- heterocycles can also be obtained from germyl- or stannyldiamines and the same β-phosphorus alcohols, thiols or amines. 2-sila 3-(oxa- or thia-) phospholanes are of particular interest for their decomposition reaction leading to silanone or silathione and phosphirane.