358-06-5Relevant articles and documents
C6F5XeY Molecules (Y = F and Cl): New synthetic approaches. first structural proof of the organoxenon halide molecule C 6F5XeF
Bilir, Vural,Frohn, Hermann-Josef
, p. 505 - 512 (2013/09/23)
The arylxenonium salt [C6F5Xe][BF4] reacts with different sources of nucleophiles, Y (naked fluoride, [N(CH 3)4]F, the silanes, (CH3)3SiCl and (C2H5)3SiH, and the cadmiumorganyl, Cd(C 6F5)2), in coordinating solvents (C 2H5CN, CH3CN, CD3CN). While the products C6F5XeF, C6F5XeCl, and (C6F5)2Xe are well defined molecules, in reactions with (C2H5)3SiH only decomposition products presumably derived from 6F5XeH6F5XeC2H56F5XeF are discussed.
Exhaustive chlorination of [B12H12]2- without chlorine gas and the use of [B12Cl12]2- as a supporting anion in catalytic hydrodefluorination of aliphatic C-F bonds
Gu, Weixing,Ozerov, Oleg V.
scheme or table, p. 2726 - 2728 (2011/05/14)
The fully chlorinated closo-dodecaborate salt Cs2[B 12Cl12] was prepared in high yield from Cs 2[B12H12] and SO2Cl2 in acetonitrile at refluxing temperature. [Ph3C]2[B 12Cl12] was obtained by simple metathesis reactions. Catalytic hydrodefluorination of benzotrifluoride sp3 C-F bonds was accomplished using [Ph3C]2[B12Cl12] as a precatalyst and Et3SiH as a stoichiometric reagent. Full consumption of the sp3 C-F bonds in p-FC6H 4CF3 and C6F5CF3 with a turnover number up to 2000 was achieved.
