36426-94-5

Basic information

• Product Name: PtH(Cl)((C(CH₃)3)(C₆H₅)2P)2
• Synonyms: PtH(Cl)((C(CH₃)3)(C₆H₅)2P)2
• CAS NO: 36426-94-5
• Molecular Weight: 716.142
• Mol File: 36426-94-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: PtH(Cl)((C(CH₃)3)(C₆H₅)2P)2(CAS DataBase Reference)
• NIST Chemistry Reference: PtH(Cl)((C(CH₃)3)(C₆H₅)2P)2(36426-94-5)
• EPA Substance Registry System: PtH(Cl)((C(CH₃)3)(C₆H₅)2P)2(36426-94-5)

Safety Data

• Hazardous Substances Data: 36426-94-5(Hazardous Substances Data)

Upstream product

• 56-23-5 tetrachloromethane 
• 71080-83-6 PtH₂(P(C₆H₅)2(C₄H₉))2 
• 6002-34-2 tert-butyldiphenylphosphine 
• 16940-66-2 sodium tetrahydroborate 
• 12080-32-9 dichloro( 1,5-cyclooctadiene)platinum(ll) 
• 79485-74-8 C₈H₁₂OCH₃PtCl(C(CH₃)3(C₆H₅)2P) 

Relevant articles and documents

Preparation and Characterization of Trichlorostannylplatinum Hydride Complexes Containing Sterically Bulky Phosphine Ligands

Trichlorostannylplatinum(II) hydride complexes containing sterically bulky phosphine ligands, trans-(R3P)2PtH(SnCl3)(1) R3P=t-BuPh2P, Cy3P, t-Bu2MeP) have been prepared by the reaction of hydrated tin(II) dichloride with respective chloro-platinum hydride complexes.A trans-geometry has been assigned for the complexes (1) on the basis of 1H and 31P NMR spectral studies.An unusually large magnitude of two-bond tin-hydrogen coupling (JSn-H ca.1598-1682 Hz) has been observed in the PMR spectra of these complexes.From the reaction of tin (II) dichloride with trans-(t-Bu3P)2PtH(Cl), surprisingly, a complex corresponding to (t-Bu3P)PtCl(SnCl3) (3) has been obtained.In solutions, one of the tri-t-butylphosphines of 3, undergoes intramolecular metalation generating a new, probably a platinum (IV) complex, .