36626-52-5 Usage
Type of compound
Ester derivative of benzyl malonic acid.
Usage
Organic synthesis (forming carbon-carbon bonds), flavoring agent in food and beverage industry, potential applications in pharmaceutical industries (synthesis of pharmaceutical compounds).
Physical property
Sweet-smelling aroma.
Additional uses
Fragrances and perfumes.
Safety precautions
Toxic and harmful if ingested or inhaled, handle with caution.
Check Digit Verification of cas no
The CAS Registry Mumber 36626-52-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,6,2 and 6 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 36626-52:
(7*3)+(6*6)+(5*6)+(4*2)+(3*6)+(2*5)+(1*2)=125
125 % 10 = 5
So 36626-52-5 is a valid CAS Registry Number.
InChI:InChI=1/C11H12O4/c12-8-14-7-6-11(15-9-13)10-4-2-1-3-5-10/h1-5,8-9,11H,6-7H2
36626-52-5Relevant articles and documents
Chemoselective Deoxygenation of 2° Benzylic Alcohols through a Sequence of Formylation and B(C6F5)3-Catalyzed Reduction
Oestreich, Martin,Richter, Sven C.
supporting information, p. 2103 - 2106 (2021/07/22)
A sequence of formylation and B(C6F5)3-catalyzed reduction of the resulting formate with Et3SiH enables the chemoselective deoxygenation of secondary benzylic alcohols. Primary benzylic and tertiary non-benzylic alcohols are not reduced by this protocol. The formyl group fulfills a double role as activator and self-sacrificing protecting group. The deoxygenation of these formates is fast and can be carried out in the presence of other potentially reducible groups. Neighboring-group participation was found in the deoxygenation of certain diol motifs.
