36707-23-0

Basic information

• Product Name: Benzene, 1-methoxy-4-[2-(4-methylphenyl)ethyl]-
• CAS NO: 36707-23-0
• Molecular Formula: C16H18O
• Molecular Weight: 226.318
• Mol File: 36707-23-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-[2-(4-methylphenyl)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-[2-(4-methylphenyl)ethyl]-(36707-23-0)
• EPA Substance Registry System: Benzene, 1-methoxy-4-[2-(4-methylphenyl)ethyl]-(36707-23-0)

Safety Data

• Hazardous Substances Data: 36707-23-0(Hazardous Substances Data)

Upstream product

• 104-82-5 4-Methylbenzyl chloride 
• 637-69-4 4-Methoxystyrene 
• 106-38-7 para-bromotoluene 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 624-31-7 4-tolyl iodide 
• 75400-50-9 9-[2-(4-methoxy-phenyl)-ethyl]-9-bora-bicyclo[3.3.1]nonane 
• 589-18-4 4-Methylbenzyl alcohol 
• 104-01-8 4-Methoxyphenylacetic acid 
• 33574-09-3 p-Methoxyphenylessigsaeure(p-methylbenzyl)ester 
• 80055-27-2 1-(4-Methoxy-phenyl)-3-p-tolyl-propan-2-one 
• 89685-74-5 4,4'-methoxymethyldibenzyl sulfone 
• 17555-94-1 (E)-4'-methoxy-4-methylstilbene 

Downstream Products

• 104-87-0 4-methyl-benzaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 

Relevant articles and documents

"bulky-Yet-Flexible" α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air

To pursue a highly regioselective and efficient reductive Heck reaction, a series of moisture-and air-stable α-diimine palladium precatalysts were rationally designed, readily synthesized, and fully characterized. The relationship between the structures of the palladium complexes and the catalytic properties was investigated. It was revealed that the"bulky-yet-flexible"palladium complexes allowed highly anti-Markovnikov-selective hydroarylation of alkenes with (hetero)aryl bromides under aerobic conditions. Further synthetic application of the present protocol could provide rapid and straightforward access to functional and biologically active molecules.

The copper-catalysed Suzuki-Miyaura coupling of alkylboron reagents: disproportionation of anionic (alkyl)(alkoxy)borates to anionic dialkylborates prior to transmetalation

We report the first example of CuI-catalysed coupling of alkylboron reagents with aryl and heteroaryl iodides that affords products in good to excellent yields. Preliminary mechanistic studies with alkylborates indicate that the anionic (alkoxy)(alkyl)borates, generated from alkyllithium and alkoxyboron reagents, undergo disproportionation to anionic dialkylborates and that both anionic alkylborates are active for transmetalation to a CuI-catalyst. Results from a radical clock experiment and the Hammett plot imply that the reaction likely proceeds via a non-radical pathway.

Photoinduced electron transfer C-C bond cleavage reactions; oxidations and isomerizations

We have shown that radical cations generated by photoinduced electron transfer (ET) in 1,2-diarylethanes, aryl pinacols, and their derivatives undergo fragmentation reactions.In the presence of oxygen oxidative products are obtained.Timerresolved laser flash photolysis and other ancillary techniques have permitted us to define the mechanisms of certian oxidative processes observed.