17555-94-1

Basic information

• Product Name: (Z)-1-methoxy-4-[2-(4-methylphenyl)ethenyl]benzene
• Synonyms: (Z)-1-methoxy-4-[2-(4-methylphenyl)ethenyl]benzene
• CAS NO: 17555-94-1
• Molecular Weight: 224.302
• Mol File: 17555-94-1.mol
• Article Data: 76

Chemical Properties

• CAS DataBase Reference: (Z)-1-methoxy-4-[2-(4-methylphenyl)ethenyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-methoxy-4-[2-(4-methylphenyl)ethenyl]benzene(17555-94-1)
• EPA Substance Registry System: (Z)-1-methoxy-4-[2-(4-methylphenyl)ethenyl]benzene(17555-94-1)

Safety Data

• Hazardous Substances Data: 17555-94-1(Hazardous Substances Data)

Upstream product

• 142087-16-9 1-(4-methylbenzyl)-1H-benzo[d][1,2,3]triazole 
• 6293-68-1 bis(4-methylphenyl)iodonium bromide 
• 768-60-5 4-methoxyphenylacetylen 
• 2746-25-0 p-Methoxybenzyl bromide 
• 1145-93-3 diethyl 4-methoxybenzylphosphonate 
• 104-87-0 4-methyl-benzaldehyde 
• 637-69-4 4-Methoxystyrene 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 106-38-7 para-bromotoluene 
• 106-49-0 p-toluidine 
• 459-44-9 4-methylbenzenediazonium tetrafluoroborate 
• 17920-15-9 (4-methylphenyl)dimethylsilanol 
• 459-64-3 4-methoxybenzenediazonium tetrafluoroborate 
• 73839-45-9 (E)-trimethyl[2-(4-methylphenyl)ethenyl]silane 

Downstream Products

• 17555-94-1 (E)-4'-methoxy-4-methylstilbene 
• 104-87-0 4-methyl-benzaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 89902-52-3 2-(4-methoxyphenyl)-2-methoxy-1-(4-methylphenyl)ethanol 
• 84857-56-7 4-methoxy 4'-diethoxyphosphonomethyl stilbene 
• 18951-45-6 (E)-1-(4-hydroxy)phenyl-2-(4-methyl)phenylethene 
• 874988-43-9 C₁₆H₁₆Br₂O 
• 14366-75-7 4-methoxy 4'-bromomethyl stilbene 
• 36707-23-0 1-(4-methylphenyl)-2-(4-methoxyphenyl)ethane 
• 127066-46-0 1-[2-methoxy-2-(4-methoxyphenyl)ethyl]-4-methylbenzene 
• 54842-60-3 1-methoxy-4-((E)-4-((E)-styryl)styryl)benzene 
• 23798-19-8 trans-1-<4-Phenyl-styryl>-4-<4-methoxy-styryl>-benzol 
• 109441-83-0 (+/-)-erythro-4-methoxy-4'-methyl-bibenzyl-α,α'-diol 
• 109441-83-0 (+/-)-threo-4-methoxy-4'-methyl-bibenzyl-α,α'-diol 

Relevant articles and documents

Transition-Metal-Free Matsuda-Heck Type Cross-Coupling and Mechanistic Evidence for a Radical Mechanism

The Matsuda-Heck reaction, usually performed with palladium catalysts, can be carried out under transition-metal-free conditions in the presence of a KOtBu/DMF couple. This system allows the selective and direct synthesis of stilbenes from aryldiazonium salts under mild temperature (20 °C). Mechanistic studies suggest a radical pathway in which the DMF acts as the initiator of the overall process.

Substituent Effects on Torsional Barriers: p-Methoxy- and p-Methoxy-p'-methyl-trans-stilbene

Jet-cooled fluorescence excitation spectra and selected single vibronic level dispersed fluorescence spectra are presented for p-methoxy-trans-stilbene and p-methoxy-p'-methyl-trans-stilbene.Two stable conformers of the methoxy group are evident in the sp

N-Heterocyclic carbene palladium (II)-pyridine (NHC-Pd (II)-Py) complex catalyzed heck reactions

A mild, efficient, and practical catalytic system for the synthesis of highly privileged stilbene pharmacophores is reported. This system uses N-heterocyclic carbene palladium (II) Pyridine (NHC-Pd (II)-Py) complex to catalyze the formation of carbon-carbon bonds between olefin derivatives and various bromide. This simple, gentle and user-friendly method can offer a variety of stilbene products in excellent yields under solvent-free condition. And its scale-up reaction has excellent yield and this system can be applied to industrial fields. The utility of this method is highlighted by its universality and modular synthesis of a series of bioactive molecules or important medical intermediates.

Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis

The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.