3969-69-5

Basic information

• Product Name: (+/-)-cis-4-hydroxymethyl-2-phenyl-1,3-dioxolane
• CAS NO: 3969-69-5
• Molecular Weight: 194.23
• Mol File: 3969-69-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (+/-)-cis-4-hydroxymethyl-2-phenyl-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-cis-4-hydroxymethyl-2-phenyl-1,3-dioxolane(3969-69-5)
• EPA Substance Registry System: (+/-)-cis-4-hydroxymethyl-2-phenyl-1,3-dioxolane(3969-69-5)

Safety Data

• Hazardous Substances Data: 3969-69-5(Hazardous Substances Data)

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 70005-88-8 (R)-1,2,4-butanetriol 
• 100-52-7 benzaldehyde 
• 3068-00-6 D,L-1,2,4-butanetriol 
• 3969-69-5 (+/-)-cis-4-hydroxymethyl-2-phenyl-1,3-dioxolane 

Downstream Products

• 103773-79-1 [(2S,4S)-2-phenyl-1,3-dioxan-4-yl]methanol 
• 3969-69-5 (-)-cis-4-hydroxymethyl-2-phenyl-1,3-dioxolane 
• 1402820-10-3 C₁₂H₁₂O₂ 
• 602314-28-3 (Z)-3-((2R,4R)-2-Phenyl-[1,3]dioxan-4-yl)-acrylic acid methyl ester 
• 134665-70-6 (Z)-3-((2R,4R)-2-Phenyl-[1,3]dioxan-4-yl)-acrylic acid methyl ester 
• 102794-92-3 (2R,4R)-4-formyl-2-phenyl-1,3-dioxane 
• 140210-14-6 (R,R)-4-(Acetoxymethyl)-2-phenyl-1,3-dioxane 
• 140210-14-6 (S,S)-4-(Acetoxymethyl)-2-phenyl-1,3-dioxane 

Relevant articles and documents

Biocatalytic synthesis of chiral polyoxygenated compounds: Modulation of the selectivity upon changes in the experimental conditions

Derivatives of both enantiomers of butane-1,2,4-triol have been obtained through a transesterification reaction catalyzed by Pseudomonas fluorescens lipase (PFL) in organic solvents. The influence of the solvent on the enantioselectivity has been thorough

Transacetalization of acetals with butane-1,2,4-triol using cobalt(II) chloride and chlorotrimethylsilane

Transacetalization of acetals with butane-1,2,4-triol was carried out using cobalt(II) chloride and chlorotrimethylsilane as catalysts. The reaction occurs under mild conditions in acetonitrile and with a short reaction time. The synergic effect of the two Lewis acids catalyzes the conversion of butane-1,2,4-triol into (2-alkyl- or 2-aryl-1,3-dioxan-4-yl)methanol derivatives with high regiospecificity and diasteroselectivity. Georg Thieme Verlag Stuttgart · New York.

New and concise approach to (R)-α-lipoic acid

A concise enantiospecific synthesis of (S)-6,8-bis(methylsulfonyloxy)- octanoic acid (2), a ready precursor of (R)-(+)-α-lipoic acid (1), is reported. The key step of the synthesis is the coupling of the tosylate derived from (R)-malic acid with phenylpro