400737-33-9

Basic information

• Product Name: tert-Butyl-{(1R,2R)-1-[(R)-3-methoxy-2-(4-methoxy-benzyloxy)-propyl]-2-methyl-but-3-enyloxy}-dimethyl-silane
• Synonyms: tert-Butyl-{(1R,2R)-1-[(R)-3-methoxy-2-(4-methoxy-benzyloxy)-propyl]-2-methyl-but-3-enyloxy}-dimethyl-silane
• CAS NO: 400737-33-9
• Molecular Weight: 408.654
• Mol File: 400737-33-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-Butyl-{(1R,2R)-1-[(R)-3-methoxy-2-(4-methoxy-benzyloxy)-propyl]-2-methyl-but-3-enyloxy}-dimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-{(1R,2R)-1-[(R)-3-methoxy-2-(4-methoxy-benzyloxy)-propyl]-2-methyl-but-3-enyloxy}-dimethyl-silane(400737-33-9)
• EPA Substance Registry System: tert-Butyl-{(1R,2R)-1-[(R)-3-methoxy-2-(4-methoxy-benzyloxy)-propyl]-2-methyl-but-3-enyloxy}-dimethyl-silane(400737-33-9)

Safety Data

• Hazardous Substances Data: 400737-33-9(Hazardous Substances Data)

Upstream product

• 400737-23-7 2-[(R)-3-Methoxy-2-(4-methoxy-benzyloxy)-propyl]-[1,3]dithiane 
• 400737-27-1 (R)-4-Methoxy-3-(4-methoxy-benzyloxy)-butyraldehyde 
• 400737-20-4 (R)-1-[1,3]Dithian-2-yl-3-methoxy-propan-2-ol 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 400737-30-6 (3R,4R,6R)-7-Methoxy-6-(4-methoxy-benzyloxy)-3-methyl-hept-1-en-4-ol 

Downstream Products

• 400737-36-2 (2S,3R,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-5-(4-methoxy-benzyloxy)-2-methyl-hexanal 
• 400737-40-8 (R)-4-Benzyl-3-[(2R,3S,4R,5R,7R)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-8-methoxy-7-(4-methoxy-benzyloxy)-2,4-dimethyl-octanoyl]-oxazolidin-2-one 
• 400737-49-7 (2R,3S,4S,5R,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-8-methoxy-7-(4-methoxy-benzyloxy)-2,4-dimethyl-3-trimethylsilanyloxy-octanal 
• 400737-43-1 (2R,3S,4R,5R,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-8-methoxy-7-(4-methoxy-benzyloxy)-2,4-dimethyl-octanoic acid methoxy-methyl-amide 
• 400737-46-4 (2R,3S,4S,5R,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-8-methoxy-7-(4-methoxy-benzyloxy)-2,4-dimethyl-3-trimethylsilanyloxy-octanoic acid methoxy-methyl-amide 
• 400736-37-0 2-[(1R,2S,3S,4R,6R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-7-methoxy-6-(4-methoxy-benzyloxy)-1,3-dimethyl-heptyl]-[1,3]dithiane 

Relevant articles and documents

Total Synthesis of Apoptolidin: Construction of Enantiomerically Pure Fragments

A general strategy for the total synthesis of the antitumor agent apoptolidin (1) is proposed, and the chemical synthesis of the defined key building blocks (4, 5, 6, 8, and 9) in their enantiomerically pure forms is described. The projected total synthes