412271-30-8

Basic information

• Product Name: Benzenemethanamine, N-(4-methoxyphenyl)-a-(1-methylethyl)-
• CAS NO: 412271-30-8
• Molecular Formula: C17H21NO
• Molecular Weight: 255.36
• Mol File: 412271-30-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-(4-methoxyphenyl)-a-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-(4-methoxyphenyl)-a-(1-methylethyl)-(412271-30-8)
• EPA Substance Registry System: Benzenemethanamine, N-(4-methoxyphenyl)-a-(1-methylethyl)-(412271-30-8)

Safety Data

• Hazardous Substances Data: 412271-30-8(Hazardous Substances Data)

Upstream product

• 1539-32-8 4-isopropyl-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid diethyl ester 
• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 75-30-9 2-iodo-propane 
• 100-52-7 benzaldehyde 
• 104-94-9 4-methoxy-aniline 
• 1068-55-9 isopropylmagnesium chloride 
• 1613-90-7 4-methoxy-N-[(E)-phenylmethylidene]aniline 
• 57181-82-5 4-bromo-isobutylbenzene 
• 5720-07-0 4-methoxyphenylboronic acid 

Downstream Products

• 1562-94-3 4,4'-azoxy anisole 
• 611-70-1 phenyl isopropyl ketone 

Relevant articles and documents

Radical alkylation of imines with 4-alkyl-1,4-dihydropyridines enabled by photoredox/br?nsted acid cocatalysis

Radical alkylation of imines with 4-alkyl-1,4-dihydropyridines cocatalyzed by iridium/ruthenium complex and Br?nsted acid under visible light irradiation has been achieved. Both aldimines and ketimines can undergo this transformation. Common functional groups, such as hydroxyl groups, ester, amide, ether, cyanide, and heterocycles, can be tolerated in this reaction. A variety of structurally diverse amines (57 examples) have been produced with up to 98% isolated yields using this method.

Synthesis, oxidation and photophysical properties of novel derivatives of acyclic aromatic amines

Conjugated acyclic arylamine derivatives, N-(4-methylphenyl)-N-(2-methyl-1- phenylpropyl)amine and N-(4-methoxyphenyl)-N-(2-methyl-1-phenylpropyl)amine, have been synthesized and characterized. Their photophysical properties have been investigated in polar methanol and non-polar cyclohexane solutions, and in PS and PMMA polymer matrices. The influence of the environment polarity as well as of the substituent in para-position of the aryl on the absorption, emission spectra and the fluorescence quantum yield has been studied. In the absorption and emission spectra, the observed absorption and emission band maxima were red shifted and the observed quantum yield was higher in the polar solution in comparison with the non-polar solution or polymer matrices. The distance of short- and long-wavelength absorption maxima in the methoxy derivative was larger and the emission band was red shifted in comparison with the methyl derivative. Chemical and photochemical oxidation of the prepared amines gives unstable nitroxides. High intramolecular quenching was observed in polymer matrix after photochemical oxidation of the amines.

Soluble lanthanide salts (LnCl3,·2 LiCl) for the improved addition of organomagnesium reagents to carbonyl compounds

(Chemical Equation Presented) Easy-to-prepare solutions of LnCl 3·2 LiCl (Ln = La, Ce, Nd) (0.3-0.5 M in THF) are a unique source of soluble lanthanide salts with versatile applications in organic synthesis. These salts can serve as promoters or catalysts for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines.