42330-51-8

Basic information

• Product Name: Benzenemethanol, a-[[(4-methylphenyl)thio]methyl]-
• CAS NO: 42330-51-8
• Molecular Formula: C15H16OS
• Molecular Weight: 244.357
• Mol File: 42330-51-8.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[[(4-methylphenyl)thio]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[[(4-methylphenyl)thio]methyl]-(42330-51-8)
• EPA Substance Registry System: Benzenemethanol, a-[[(4-methylphenyl)thio]methyl]-(42330-51-8)

Safety Data

• Hazardous Substances Data: 42330-51-8(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 103-19-5 di(p-tolyl) disulfide 
• 106-45-6 para-thiocresol 
• 114245-60-2 (bromomethyl)(4-methylphenyl)sulfane 
• 100-52-7 benzaldehyde 
• 38078-55-6 sodium S-(4-methylphenyl) thiosulfate 
• 96-09-3 styrene oxide 
• 1427290-14-9 1-(phenylseleno)-1,1-(S_S,S_S)-bis(p-tolylsulfinyl)methane 
• 52154-24-2 (R)-p-tolylsulfinylacetophenone 
• 98-59-9 p-toluenesulfonyl chloride 
• 536-57-2 p-toluene sulfinic acid 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 6873-93-4 1-[(4-methylphenyl)sulfinyl]piperidine 
• 1674-30-2 1-phenyl-2-chloroethanol 

Downstream Products

• 16212-08-1 1-methyl-4-((2-phenylallyl)sulfonyl)benzene 
• 71899-75-7 2-hydroxy-2-phenylethyl 4-methylphenyl sulfone 
• 20780-53-4 (R)-Styrene oxide 
• 20780-54-5 (S)-styrene oxide 

Relevant articles and documents

HBr/H2O2-mediated formation of C–S bond with thiosulfates

A novel, efficient, and green protocol to construct C–S bond has been developed via HBr/H2O2-mediated sulfenylation of styrenes and 4-hydroxycoumarins leading to unsymmetrical sulfides. Various unsymmetrical sulfides were prepared in one step with moderate to good yields using environmentally-friendly H2O2 as oxidant and HBr as catalyst. Based on the preliminary experimental results, a plausible reaction mechanism was proposed for HBr/H2O2-mediated formation of C–S bond with thiosulfates.

Br?nsted Acid-Assisted Zinc-Catalyzed Markovnikov-Type Hydrothiolation of Alkenes Using Thiols

The zinc-catalyzed regioselective hydrothiolation of alkenes with thiols was achieved in the presence of 4-toluenesulfonic acid. Through this procedure, Markovnikov-type sulfides were synthesized in excellent yields, and the formation of anti-Markovnikov-

Molecular Iodine Catalyzed Hydroxysulfenylation of Alkenes with Disulfides in Aerobic Conditions

An environmentally friendly and efficient strategy has been developed for preparing β-hydroxy sulfides by a molecular-iodine-catalyzed radical reaction. This reaction involves hydroxysulfenylation of alkenes with disulfides in aqueous solution. Air is use