433735-02-5

Basic information

• Product Name: (S)-N-benzyl-N-chloroacetylvaline methyl ester
• Synonyms: (S)-N-benzyl-N-chloroacetylvaline methyl ester
• CAS NO: 433735-02-5
• Molecular Weight: 297.782
• Mol File: 433735-02-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-N-benzyl-N-chloroacetylvaline methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-benzyl-N-chloroacetylvaline methyl ester(433735-02-5)
• EPA Substance Registry System: (S)-N-benzyl-N-chloroacetylvaline methyl ester(433735-02-5)

Safety Data

• Hazardous Substances Data: 433735-02-5(Hazardous Substances Data)

Upstream product

• 40216-62-4 N-benzyl-L-valine methyl ester 
• 79-04-9 chloroacetyl chloride 
• 100-39-0 benzyl bromide 
• 4070-48-8 L-Valine methyl ester 

Downstream Products

• 433735-11-6 1-[(3'R,6'S)-1'-benzyl-3'-benzyloxycarbonylmethyl-5'-ethoxy-(6'H)-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane 
• 433735-10-5 1-[(3'R,6'S)-3'-allyl-1'-benzyl-5'-ethoxy-(6'H)-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane 
• 433735-12-7 1-[(3'R,6'S)-1'-benzyl-3'-chloromethyl-5'-ethoxy-(6'H)-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane 
• 433735-04-7 1-[(3'R,6'S)-1'-benzyl-5'-ethoxy-3',6'-dihydro-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane 
• 433735-03-6 (6S)-1-benzyl-5-ethoxy-3,6-dihydro-6-isopropylpyrazine-2-one 
• 427888-21-9 (2S)-1-N-benzyl-2-isopropyl-piperazine-3,6-dione 

Relevant articles and documents

A new stereocontrolled synthesis of uncommon tripeptides derived from 2,6-diaminopimelic acid (2,6-DAP)

The stereocontrolled synthesis of uncommon tripeptides 8 and 11a-c, structural variants of 2,6-diaminopimelic acid, was carried out starting from the mono-lactim ether 1 easily obtained from L-valine. The configurations of the introduced stereogenic centers were assigned on the basis of 1H NMR spectroscopic data.