433735-04-7

Basic information

• Product Name: 1-[(3'R,6'S)-1'-benzyl-5'-ethoxy-3',6'-dihydro-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane
• Synonyms: 1-[(3'R,6'S)-1'-benzyl-5'-ethoxy-3',6'-dihydro-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane
• CAS NO: 433735-04-7
• Molecular Weight: 588.791
• Mol File: 433735-04-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[(3'R,6'S)-1'-benzyl-5'-ethoxy-3',6'-dihydro-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(3'R,6'S)-1'-benzyl-5'-ethoxy-3',6'-dihydro-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane(433735-04-7)
• EPA Substance Registry System: 1-[(3'R,6'S)-1'-benzyl-5'-ethoxy-3',6'-dihydro-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane(433735-04-7)

Safety Data

• Hazardous Substances Data: 433735-04-7(Hazardous Substances Data)

Upstream product

• 433735-02-5 (S)-N-benzyl-N-chloroacetylvaline methyl ester 
• 427888-21-9 (2S)-1-N-benzyl-2-isopropyl-piperazine-3,6-dione 
• 40216-62-4 N-benzyl-L-valine methyl ester 
• 100-39-0 benzyl bromide 
• 4070-48-8 L-Valine methyl ester 
• 627-31-6 1,3-Diiodopropane 
• 433735-03-6 (6S)-1-benzyl-5-ethoxy-3,6-dihydro-6-isopropylpyrazine-2-one 

Downstream Products

• 433735-12-7 1-[(3'R,6'S)-1'-benzyl-3'-chloromethyl-5'-ethoxy-(6'H)-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane 
• 433735-10-5 1-[(3'R,6'S)-3'-allyl-1'-benzyl-5'-ethoxy-(6'H)-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane 
• 433735-11-6 1-[(3'R,6'S)-1'-benzyl-3'-benzyloxycarbonylmethyl-5'-ethoxy-(6'H)-6'-isopropylpyrazin-3'-yl-2'-one]-3-[(3''R,6''S)-1''-benzyl-5''-ethoxy-3'',6''-dihydro-6''-isopropylpyrazin-3''-yl-2''-one]propane 
• 618462-36-5 (3R,6S)-1-Benzyl-3-[3-((2R,5S)-4-benzyl-6-ethoxy-5-isopropyl-3-oxo-2,3,4,5-tetrahydro-pyrazin-2-yl)-propyl]-3-(3-chloro-propyl)-5-ethoxy-6-isopropyl-3,6-dihydro-1H-pyrazin-2-one 
• 618462-50-3 (3S,8aR)-8a-[3-((2R,5S)-2-Benzyl-6-ethoxy-5-isopropyl-3-oxo-2,3,4,5-tetrahydro-pyrazin-2-yl)-propyl]-3-isopropyl-hexahydro-pyrrolo[1,2-a]pyrazine-1,4-dione 
• 618462-37-6 (3S,8aR)-2-Benzyl-8a-[3-((2R,5S)-4-benzyl-6-ethoxy-5-isopropyl-3-oxo-2,3,4,5-tetrahydro-pyrazin-2-yl)-propyl]-3-isopropyl-hexahydro-pyrrolo[1,2-a]pyrazine-1,4-dione 
• 618462-47-8 (3S,8aR)-2-Benzyl-8a-[3-((2S,5S)-4-benzyl-6-ethoxy-5-isopropyl-2-methyl-3-oxo-2,3,4,5-tetrahydro-pyrazin-2-yl)-propyl]-3-isopropyl-hexahydro-pyrrolo[1,2-a]pyrazine-1,4-dione 
• 618462-48-9 (3S,8aR)-2-Benzyl-8a-[3-((2R,5S)-2,4-dibenzyl-6-ethoxy-5-isopropyl-3-oxo-2,3,4,5-tetrahydro-pyrazin-2-yl)-propyl]-3-isopropyl-hexahydro-pyrrolo[1,2-a]pyrazine-1,4-dione 

Relevant articles and documents

A new stereocontrolled synthesis of uncommon tripeptides derived from 2,6-diaminopimelic acid (2,6-DAP)

The stereocontrolled synthesis of uncommon tripeptides 8 and 11a-c, structural variants of 2,6-diaminopimelic acid, was carried out starting from the mono-lactim ether 1 easily obtained from L-valine. The configurations of the introduced stereogenic centers were assigned on the basis of 1H NMR spectroscopic data.