4418-61-5Relevant articles and documents
Rapidly, highly yielded and green synthesis of dihydrotetrazolo[1,5-a]pyrimidine derivatives in aqueous media using recoverable Pd (II) thiazole catalyst accelerated by ultrasonic: Computational studies
Abu-Dief, Ahmed M.,Alsoliemy, Amerah,El-Dabea, Tarek,El-Metwaly, Nashwa M.,El-Remaily, Mahmoud Abd El Aleem Ali Ali,Khalifa, Mohamed E.,Soliman, Ahmed M. M.
, (2021/07/02)
Here, we synthesized new thiazole complexes from Cu (II), Fe (III), and Pd (II) ions. Such complexes were characterized to present their chemical formulae, firstly. The octahedral geometry was suggested for the investigated complexes except Pd (II) complex (ARPTPd), which has a square-planer arrangement. ARPTPd was planned to be used as a catalyst for synthesis of dihydrotetrazolo[1,5-a]pyrimidine derivatives at mild conditions. The catalytic activity of ARPTPd complex in four-components reaction approach was deliberately monitored till it reaches the most favorable conditions. The advantages of suggested catalyst were basically summarized by using green solvent (H2O), lower reaction time, and high products yields. Also, the superiority of ARPTPd complex and ultrasonic irradiation towards synthesis of dihydrotetrazolo[1,5-a]pyrimidine derivatives was revealed compared with other Lewis acids, basic, and ionic liquid catalysts. Furthermore, the mildness of conversion and compatibility with different functional groups makes it attractive. In addition, in consecration, computational aspects were often taken according to their effect on the declaration or discrimination of variable functional characteristics. Crystal packing systems of complexes were configured to extract important surface properties. DFT study was also applied to explain the causes behind the superiorly of ARPTPd complex. Also, the optimization process for intermediates was executed to support the suggested mechanism. Finally, this simple, economical, and green catalytic procedure may be applied to the industry in future.
Production process of 5-aminotetrazole
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Paragraph 0017-0024, (2021/01/15)
The invention belongs to the technical field of chemical synthesis, and particularly discloses a production process of 5-aminotetrazole, which adopts the following synthesis route: aminoguanidine bicarbonate and sulfuric acid are adopted to generate aminoguanidine sulfate; diazotization reaction is carried out on aminoguanidine sulfate and sodium nitrite to generate amidine azide sulfate; and cyclization reaction is performed on the amidine azide sulfate under the action of ammonia water to generate the 5-amino tetrazole. The path is good in safety and few in byproducts; the invention also provides a specific process flow, the process is simple, the operation is easy, and the product yield is high; according to the invention, a high-purity 5-amino tetrazole finished product is obtained bystep-by-step conversion in the diazotization process, control of the addition mode of sodium nitrite and strict control of the temperature and pH in the diazotization and cyclization reaction processes.
Synthesis of 5 - amino tetrazole method
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Paragraph 0028; 0029; 0030, (2019/06/13)
Synthesis of 5 - amino tetrazole method, in order to hydrazine hydrate, lime nitrogen, sodium nitrite, inorganic acid and inorganic base as the obtained 5 - amino tetrazole. The method through the metathesis reaction, addition reaction and diazo isomerization reaction of the cyano lead lime nitrogen into the aminoguanidine, then generating aminoguandine isomerization reaction to synthesize 5 - amino tetrazole. The invention compared with the traditional method, has the following advantages: (1) price cheap raw materials as the starting raw material, synthetic product is obtained; (2) simplified 5 - amino tetrazole operation process, reduce the reaction solvent types and process the complexity of the operation, reduces the cost of material and production cost, reduces the 5 - amino tetrazole synthesis cost of, improve the market competitiveness of the product. It has high efficiency, high yield, low cost, easy operation and the like.