443797-88-4

Basic information

• Product Name: [(C₅(CH₃)5)Fe(1,2,4-(C₆H₅)3C₆H₃)]PF₆
• CAS NO: 443797-88-4
• Molecular Weight: 642.447
• Mol File: 443797-88-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₅(CH₃)5)Fe(1,2,4-(C₆H₅)3C₆H₃)]PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: [(C₅(CH₃)5)Fe(1,2,4-(C₆H₅)3C₆H₃)]PF₆(443797-88-4)
• EPA Substance Registry System: [(C₅(CH₃)5)Fe(1,2,4-(C₆H₅)3C₆H₃)]PF₆(443797-88-4)

Safety Data

• Hazardous Substances Data: 443797-88-4(Hazardous Substances Data)

Upstream product

• 86991-88-0 [(η5-pentamethylcyclopentadienyl)iron(acetonitrile)3]PF6 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Alkyne coupling reactions mediated by iron (II) complexes: Highly chemo- And regioselective formation of η6-coordinated arene and pyridine complexes

Reaction of the bis(acetonitrile) complex 1 with HC≡CPh affords the (allyl)carbene complex 3, which results from a head-to-tail coupling of two alkynes. The tris(acetonitrile) complex [Fe(C5Me5)(CH3CN)3][PF6] (2) mediates highly chemo- And regioselective [2 + 2 + 2] cycloaddition reactions of C≡C and C≡N triple bonds, providing access to π-arene and -pyridine complexes. The pyridine complex 5a has been characterized by an X-ray crystal structure.