50518-68-8

Basic information

• Product Name: diphenylantimony(III) bromide
• Synonyms: diphenylantimony(III) bromide
• CAS NO: 50518-68-8
• Molecular Weight: 355.865
• Mol File: 50518-68-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: diphenylantimony(III) bromide(CAS DataBase Reference)
• NIST Chemistry Reference: diphenylantimony(III) bromide(50518-68-8)
• EPA Substance Registry System: diphenylantimony(III) bromide(50518-68-8)

Safety Data

• Hazardous Substances Data: 50518-68-8(Hazardous Substances Data)

Upstream product

• 152582-21-3 phenylantimony(III) bis(7-chloroisatin) 
• 102829-02-7 diphenylantimony(V) bromide oxide 
• 124782-44-1 diphenylantimony(III) phthalimide 
• 20265-30-9 triphenylantimony dibromide 
• 5613-52-5 diphenylantimony(III) acetate 
• 7440-36-0 antimony 
• 108-86-1 bromobenzene 
• 2629-47-2 diphenylantimony(III) chloride 
• 7647-15-6 sodium bromide 
• 603-36-1 triphenylantimony 
• 7789-61-9 antimony(III) bromide 

Downstream Products

• 102829-02-7 ((C₆H₅)2SbBrO)2 
• 50518-69-9 (C₆H₅)2SbBr₂C₆H₄-4-N(CH₃)2 
• 942131-96-6 [W(CO)5(SbBr(C₆H₅)2)] 
• 62170-61-0 diphenylantimony(V) tribromide 
• 157808-15-6 diphenylantimony(V) bromide dichloride 
• 861805-80-3 diphenyl(p-tolylethynyl)stibane 
• 289473-26-3 1-hexynylethynyldiphenylstibane 
• 861805-81-4 3,3-dimethyl-1-butynyldiphenylstibane 
• 289473-25-2 diphenyl(trimethylsilylethynyl)stibine 
• 289473-23-0 diphenyl(p-methoxyphenylethynyl)stibine 
• 289473-24-1 diphenyl(p-fluorophenylethynyl)stibine 

Relevant articles and documents

Syntheses, structures and DFT study of [W(CO)5(Ph2SbX)] X = Cl, Br, I

The complexes [W(CO)5(Ph2SbX)], X = Cl (1), Br (2) and I (3) were prepared by reaction of [W(CO)5(tetrahydrofuran)] with Ph2SbX. The structures of 1-3 were studied by X-ray diffraction. In the crystals there are weak contacts between the oxygen atoms of the CO ligands and antimony atoms of neighbouring molecules. DFT calculations were carried out for 1 using gradient corrected functional B3LYP. The bonding between Ph2SbCl and the W(CO)5 fragment in 1 was analysed using charge decomposition analysis.

Reduction of antimony(V) by dithiophosphinates and the crystal structure of dimeric diphenylantimony(III) dimethyldithiophosphinate

Reactions between three diorganodithiophosphinates and diphenylantimony(V) bromide oxide (SbPh2OBr)2, led to antimony reduction while dithiophosphinate oxidation followed a complex path varying in detail with the nature of the organic groups on dithiophosphinate. Antimony(III) dithiophosphinates, SbPh2(S2PR2) where R = Me, Et and Ph, have been isolated and characterised and an X-ray structure determination for the methyl derivative shows weakly associated dimers in the solid state, intermediate between those in (SbPh2S2PPh2)2 and [Sb(4-MeC6H4)2S2PEt]2. Copyright