942131-96-6

Basic information

• Product Name: [W(CO)5(SbBr(C₆H₅)2)]
• CAS NO: 942131-96-6
• Molecular Weight: 679.767
• Mol File: 942131-96-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [W(CO)5(SbBr(C₆H₅)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [W(CO)5(SbBr(C₆H₅)2)](942131-96-6)
• EPA Substance Registry System: [W(CO)5(SbBr(C₆H₅)2)](942131-96-6)

Safety Data

• Hazardous Substances Data: 942131-96-6(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 14040-11-0 tungsten hexacarbonyl 
• 50518-68-8 diphenylantimony(III) bromide 
• 2629-47-2 diphenylantimony(III) chloride 

Relevant articles and documents

Syntheses, structures and DFT study of [W(CO)5(Ph2SbX)] X = Cl, Br, I

The complexes [W(CO)5(Ph2SbX)], X = Cl (1), Br (2) and I (3) were prepared by reaction of [W(CO)5(tetrahydrofuran)] with Ph2SbX. The structures of 1-3 were studied by X-ray diffraction. In the crystals there are weak contacts between the oxygen atoms of the CO ligands and antimony atoms of neighbouring molecules. DFT calculations were carried out for 1 using gradient corrected functional B3LYP. The bonding between Ph2SbCl and the W(CO)5 fragment in 1 was analysed using charge decomposition analysis.