53067-09-7Relevant articles and documents
PROCESS FOR PRODUCING HYDROXYMETHYL-ALCOHOLS
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Page/Page column 28, (2020/06/19)
The present invention relates to a process for producing an organic compound A, which comprises at least one primary alcoholic hydroxy group and at least one secondary alcoholic hydroxy group, comprising a process step, wherein a compound B, which comprises at least one nitrile group and at least one ketone group, is reacted with hydrogen and water in the presence of at least one homogeneous transition metal catalyst TMC 1.
Bent bonds (τ) and the antiperiplanar hypothesis, and the reactivity at the anomeric center in pyranosides
Parent, Jean-Fran?ois,Deslongchamps, Pierre
, p. 11183 - 11198 (2016/12/09)
The stereoselectivity of nucleophilic addition on oxocarbenium ions derived from the bicyclic pyranoside model with or without a C2-OR group can be understood through the use of the bent-bond and the antiperiplanar hypothesis in conjunction with the concept of hyperconjugation as an alternative interpretive model of structure and reactivity.
An unusual reaction of cyclic enol ethers with titanium(III) tetrahydroborate
Ravikumar,Chandrasekaran, Srinivasan
, p. 2973 - 2978 (2007/10/03)
Titanium(III) Tetrahydroborate formed in situ from titanium tetrachloride and benzyltriethylammonium tetrahydroborate (1:4) readily reacts with cyclic enol ethers in dichloromethane at -20°C to give the corresponding acyclic diols in high yields after simple aqueous work-up.