550348-56-6

Basic information

• Product Name: Benzaldehyde, 4-(4-bromo-5-methyl-2-thienyl)-
• CAS NO: 550348-56-6
• Molecular Formula: C12H9BrOS
• Molecular Weight: 281.173
• Mol File: 550348-56-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 4-(4-bromo-5-methyl-2-thienyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 4-(4-bromo-5-methyl-2-thienyl)-(550348-56-6)
• EPA Substance Registry System: Benzaldehyde, 4-(4-bromo-5-methyl-2-thienyl)-(550348-56-6)

Safety Data

• Hazardous Substances Data: 550348-56-6(Hazardous Substances Data)

Upstream product

• 29421-73-6 3,5-dibromo-2-methylthiophene 
• 1089333-62-9 4-(5-methylthiophen-2-yl)benzaldehyde 
• 1310404-98-8 2-(4-bromo-5-methylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1122-91-4 4-bromo-benzaldehyde 
• 554-14-3 2-Methylthiophene 
• 154566-69-5 3-bromo-2-methylthiophene-5-boronic acid 

Downstream Products

• 1312716-02-1 C₃₁H₂₄F₆O₃S₂ 
• 1312716-01-0 1-[2-methyl-5-(4-methoxylphenyl)-3-thienyl]-2-[2-methyl-5-(4-formylphenyl)-3-thienyl]perfluorocyclopentene 
• 210093-64-4 1,2-bis[2-methyl-5-(p-(hydroxymethyl)phenyl)-3-thienyl]hexafluorocyclopentene 
• 210093-65-5 1,2-bis(2-methyl-5-(4-bromobenzyl)thiophen-3-yl)hexafluorocyclopentene 
• 1427283-27-9 1-(2-methyl-1-benzofuran-3-yl)-2-[2-methyl-5-(4-1,3-dioxolane-phenyl)-3-thienyl]perfluorocyclopentene 
• 1586038-80-3 1-(2-methyl-1-benzofuran-3-yl)-2-[2-methyl-5-(4-benzaldehyde)-3-thienyl]perfluorocyclopentene 
• 1372715-06-4 1-(2-methylnaphth-1-yl)-2-[2-methyl-5-(4-(1,3-dioxolan-2-yl)phenyl)thien-3-yl]perfluorocyclopentene 
• 1375061-65-6 C₃₄H₂₄F₆O₂S₃ 
• 1344734-19-5 C₃₅H₂₄F₆O₂S₂ 
• 1344734-18-4 1-[2-methyl-5-(4-formylphenyl)-3-thienyl]-2-(2-methyl-3-benzothiophenyl) perfluorocyclopentene 
• 1344734-12-8 C₄₁H₂₈F₆O₂S₃ 
• 1344734-09-3 C₃₂H₂₀F₆OS₃ 
• 550348-59-9 (S)-1-[5-(4-(3-methylpent-1-enyl)phenyl)-2-methyl-3-thienyl]-2-(2-methyl-5-phenyl-3-thienyl)hexafluorocyclopentene 
• 550348-58-8 1-[5-(4-(1,3-dioxolan-2-yl)phenyl)-2-methyl-3-thienyl]-2-(2-methyl-5-phenyl-3-thienyl)hexafluorocyclopentene 

Relevant articles and documents

Diastereoselective cyclization in chiral diarylethene crystals: Polymorphism and selectivity

(Matrix presented) An optically active photochromic diarylethene, (s)-1-(2-methyl-5-phenyl-3-thienyl)-2-[2-methyl-5-(4-(3-methyl-1-penten-1-yl) phenyl)-3-thienyl]-perfluorocyclopentene ((S)-1a), was synthesized. (S)-1a formed two crystalline phases, α- an

Asymmetric octafluorocyclopentene compound with continuous selectivity for Hg2+ and Cys, preparation method and application thereof

The invention discloses [1-[2-methyl-3-benzothiophene], 2-(2-methyl-5-(4-phenyl)-(2-benzoylquinoline-8-benzothiazolyl)-3-thienyl)] octafluorocyclopentene, a preparation method and an application thereof. The preparation method comprises the following steps: by taking benzothiophene as a raw material, replacing by methyl iodide and bromizing and then reacting with octafluorocyclopentene, thereby generating mono-substituted octafluorocyclopentene; by taking 2-thiotolene as a raw material, bromizing and causing n-butyllithium to react with tributyl borate; connecting aldehyde-terminated benzene with thiophene ring through Stuzki coupling; protecting by adopting ethylene glycol and then reacting with the mono-substituted octafluorocyclopentene; reducing into alcoholic hydroxyl group and becoming methylene-containing bromine; reacting with 8-hydroxyquinoline-2-aldehyde group; and finally reacting with 2-amino thiophenol, thereby acquiring a target compound. The compound prepared according to the invention can be used for continuously detecting specific ions and amino acid and has an excellent selectivity.

The effect of the formyl group position upon asymmetric isomeric diarylethenes bearing a naphthalene moiety

Three new isomeric asymmetric diarylethenes with a naphthyl moiety and a formyl group at the para, meta or ortho position of the terminal benzene ring were synthesized. Their photochromism, fluorescent-switch, and electrochemical properties were investiga