56967-17-0

Basic information

• Product Name: Benzenamine, 3-bromo-, hydrochloride
• Synonyms: m-bromoaniline hydrochloride;Benzenamine,3-bromo-,hydrochloride;3-bromoaniline hydrochloride;3-bromoanilinium chloride;m-Brom-anilin-hydrochlorid
• CAS NO: 56967-17-0
• Molecular Formula: C6H6BrN.ClH
• Molecular Weight: 208.485
• Mol File: 56967-17-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzenamine, 3-bromo-, hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 3-bromo-, hydrochloride(56967-17-0)
• EPA Substance Registry System: Benzenamine, 3-bromo-, hydrochloride(56967-17-0)

Safety Data

• Hazardous Substances Data: 56967-17-0(Hazardous Substances Data)

Upstream product

• 2564-03-6 [(3-bromophenyl)-aminocarbonylmethyl]chloride 
• 585-79-5 m-nitrobromobenzene 
• 591-19-5 m-Bromoaniline 
• 100-14-1 4-nitrobenzyl chloride 

Downstream Products

• 57727-51-2 2-(2-(3-bromophenyl)hydrazinyl)-2-oxoacetic acid 
• 20358-05-8 7-bromo-1,3-benzothiazol-2-amine 
• 20358-03-6 5‐bromo‐1,3‐benzothiazol‐2‐amine 
• 1309261-67-3 3-(7-bromo-1,3-benzothiazol-2-yl)-2-phenylquinazolin-4(3H)-one 
• 1309261-61-7 3-(5-bromo-1,3-benzothiazol-2-yl)-2-phenylquinazolin-4(3H)-one 
• 21327-14-0 1-(3-bromophenyl)thiourea 
• 1252661-54-3 di-tert-butyl (2S,4Z)-4-[(3-bromoanilino)methylidene]-5-oxopyrrolidine-1,2-dicarboxylate 
• 171178-25-9 4-(3-bromoanilino)-7-fluoropyrido[4,3-d]pyrimidine 
• 198961-91-0 4-([3-bromophenyl]amino)-6-nitrobenzothieno[3,2-d]pyrimidine 
• 14088-81-4 N'-(3-bromo-phenyl)-ethane-1,2-diamine 

Relevant articles and documents

Selective and Additive-Free Hydrogenation of Nitroarenes Mediated by a DMSO-Tagged Molecular Cobalt Corrole Catalyst

We report on the first cobalt corrole that effectively mediates the homogeneous hydrogenation of structurally diverse nitroarenes to afford the corresponding amines. The given catalyst is easily assembled prior to use from 4-tert-butylbenzaldehyde and pyrrole followed by metalation of the resulting corrole macrocycle with cobalt(II) acetate. The thus-prepared complex is self-contained in that the hydrogenation protocol is free from the requirement for adding any auxiliary reagent to elicit the catalytic activity of the applied metal complex. Moreover, a containment system is not required for the assembly of the hydrogenation reaction set-up as both the autoclave and the reaction vessels are readily charged under a regular laboratory atmosphere.

A facile and efficient method for the selective deacylation of N-arylacetamides and 2-chloro-Narylacetamides catalyzed by SOCl2

Thionyl chloride efficiently and selectively promoted the deacylation of N-arylacetamides and 2-chloro-N-arylacetamides, under anhydrous conditions, without effecting the ester group, aminosulfonyl group, or benzyloxyamide group. This method, which has been successfully applied to a variety of substrates including different N-arylacetamides and 2-chloro-N-arylacetamides, has the attractive advantages of inexpensive reagents, satisfactory selectivity, excellent yields, short reaction time, and convenient workup. This new method can probably be used to selectively deacylate between aromatic amides and alkyl amides. Springer Science+Business Media B.V. 2011.

Alternative method for the reduction of aromatic nitro to amine using TMDS-iron catalyst system

The system 1,1,3,3-tetramethyldisiloxane (TMDS)/Fe(acac)3 is reported here as a new method to obtain amines from aromatic nitro compounds. Amines are synthetized in a straightforward step and are isolated as hydrochloride salts with good to excellent yields. This system has shown a good selectivity toward aryl-chloride, aryl-bromide, ester, carboxylic acid, and cyano groups. The reduction of alkylnitro compounds was unfortunately not possible using this method, only a mixture of mono and dialkylated amine was obtained.