59090-57-2

Basic information

• Product Name: [1,1'-biphenyl]-4-yl(phenyl)sulfane
• Synonyms: [1,1'-biphenyl]-4-yl(phenyl)sulfane
• CAS NO: 59090-57-2
• Molecular Weight: 262.375
• Mol File: 59090-57-2.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: [1,1'-biphenyl]-4-yl(phenyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-biphenyl]-4-yl(phenyl)sulfane(59090-57-2)
• EPA Substance Registry System: [1,1'-biphenyl]-4-yl(phenyl)sulfane(59090-57-2)

Safety Data

• Hazardous Substances Data: 59090-57-2(Hazardous Substances Data)

Usage

Description

[1,1'-biphenyl]-4-yl(phenyl)sulfane, also known as diphenyl(phenylthio)biphenyl, is a chemical compound that features a biphenyl group with a phenylsulfanyl substituent attached to one of the phenyl rings. [1,1'-biphenyl]-4-yl(phenyl)sulfane is recognized for its significance in organic synthesis and as a key building block in the creation of a variety of organic compounds. Its structure and properties have attracted interest in the field of materials science, particularly for its potential applications in the development of organic electronics and optoelectronic devices. However, it is crucial to handle and dispose of this chemical with caution, as it may present risks to human health and the environment if not managed properly.

Uses

Used in Organic Synthesis:
[1,1'-biphenyl]-4-yl(phenyl)sulfane is utilized as an intermediate in organic synthesis, serving as a crucial component in the formation of various organic compounds. Its unique structure allows for a wide range of chemical reactions, making it a valuable asset in the synthesis of complex molecules.
Used in Materials Science:
In the field of materials science, [1,1'-biphenyl]-4-yl(phenyl)sulfane is explored for its potential applications in the development of organic electronics and optoelectronic devices. Its electronic properties and structural characteristics make it a promising candidate for use in these advanced technologies.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, given its structural complexity and potential for modification, [1,1'-biphenyl]-4-yl(phenyl)sulfane could potentially be used in the pharmaceutical industry as a starting material for the development of new drugs or drug candidates, particularly in the areas of medicinal chemistry and drug design.
Used in Chemical Research:
[1,1'-biphenyl]-4-yl(phenyl)sulfane may also be employed in academic and industrial research settings to study its chemical properties, reactivity, and potential applications in various chemical processes and reactions. This can lead to a better understanding of its behavior and the discovery of new uses for this compound.

Upstream product

• 19262-78-3 biphenyldiazonium 
• 108-98-5 thiophenol 
• 3353-89-7 triphenylsulfonium bromide 
• 66003-78-9 triphenylsulfonium trifluoromethanesulfonate 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 98-80-6 phenylboronic acid 
• 14002-51-8 4-biphenyl-carboxylic acid chloride 
• 144317-44-2 triphenylsulfonium nonafluoro-n-butanesulfonate 
• 75-05-8 acetonitrile 
• 1591-31-7 4-iodo-biphenyl 
• 882-33-7 diphenyldisulfane 
• 591-50-4 iodobenzene 
• 92-66-0 4-bromo-1,1'-biphenyl 
• 5122-94-1 4-biphenylboronic acid 

Downstream Products

• 1357466-07-9 [4-(4-biphenylylthio)phenyl]-(4-biphenylyl)phenylsulfonium hexafluorophosphate 
• 1215851-50-5 [4-(4-biphenylylthio)phenyl]-4-biphenylylphenylsulfonium tris(pentafluoroethyl)trifluorophosphate 
• 1357467-32-3 [4-(4-biphenylylthio)phenyl]-4-biphenylylphenylsulfonium tetrakis(pentafluorophenyl)borate 
• 1240786-54-2 [4-(4-biphenylthio)phenyl]-4-biphenylphenylsulfonium triflate 
• 1357466-08-0 [4-(4-biphenylylthio)phenyl]-4-biphenylylphenylsulfonium methanesulfonate 
• 21213-15-0 4-[(phenyl)sulfinyl]biphenyl 
• 1230-51-9 4-(phenylsulfonyl)biphenyl 

Relevant articles and documents

Aryl thioether compound and preparation method thereof

The invention discloses an aryl thioether compound and a synthesis method thereof, wherein an aryl carboxylic acid and a mercaptan (phenol) are used as main raw materials, and a nickel catalyst is prepared. Under the action of the phosphine ligand and the additive, the aryl carboxylic acid and the thiol (phenol) react in an organic solvent, and after the reaction is finished, the corresponding aryl thioether is obtained. The method has the advantages of low cost, high yield, simple and convenient operation, no pollution and the like, and has potential industrial application prospects. The method provides a cheap and green way for preparation of aryl thioether compounds.

DABCO-promoted Diaryl Thioether Formation by Metal-catalyzed Coupling of Sodium Sulfinates and Aryl Iodides

A scalable catalytic synthesis method using commodity chemicals for constructing diaryl thioethers directly from sodium arylsulfinates and iodoarenes is reported in this study. In the presence of CuO or other copper salts such as Cu(OAc)2 as well as palladium catalysts, DABCO demonstrated to be essential to promote this transformation. Various iodoarenes and aryl sulfinates were examined and demonstrated the viability of this method. The mechanistic study showed that radical reactions occurred, while DABCO N-oxide radical can be observed by mass spectrometry. A plausible catalytic mechanism involving DABCO is also discussed, suggesting synergistic reduction of sulfinate by Cu(II) and DABCO is the key step of this coupling reaction. (Figure presented.).

Cu-Mediated arylselenylation of aryl halides with trifluoromethyl aryl selenonium ylides

An unprecedented arylselenylation of aryl halides with trifluoromethyl aryl selenonium ylides in the presence of copper is described. The reaction proceeded at 100-140 °C under ligand- and additive-free conditions for 3-20 h to form a variety of unsymmetrical diaryl selenides in good to high yields. Arylselenylation is easy to operate, has good functional group tolerance, and demonstrates the different reaction profiles of trifluoromethyl aryl selenonium ylides from the homologous trifluoromethyl aryl sulfonium ylides.