613-47-8

Basic information

• Product Name: 2-Naphthalenamine,N-hydroxy-(9CI)
• Synonyms: 2-Naphthalenamine,N-hydroxy-(9CI);N-hydroxy-2-naphthylamine;2-NAPHTHYLHYDROXYLAMINE;2-HYDROXYLAMINONAPHTHALENE;N-HYDROXY-2-AMINONAPHTHALENE;N-2-NAPHTHYLHYDROXYLAMINE;2-Naphtylhydroxyamine;N-(2-Naphtyl)hydroxylamine
• CAS NO: 613-47-8
• Molecular Formula: C₁₀H₉NO
• Molecular Weight: 159.20
• Product Categories: BIPHENYL
• Mol File: 613-47-8.mol
• Article Data: 5

Chemical Properties

• Melting Point: 136°C (rough estimate)
• Boiling Point: 284.68°C (rough estimate)
• Flash Point: 174.9°C
• Appearance: /
• Density: 1.1202 (rough estimate)
• Vapor Pressure: 3.47E-05mmHg at 25°C
• Refractive Index: 1.5460 (estimate)
• CAS DataBase Reference: 2-Naphthalenamine,N-hydroxy-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Naphthalenamine,N-hydroxy-(9CI)(613-47-8)
• EPA Substance Registry System: 2-Naphthalenamine,N-hydroxy-(9CI)(613-47-8)

Safety Data

• Hazardous Substances Data: 613-47-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H9NO/c12-11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7,11-12H

Upstream product

• 581-89-5 2-nitronaphthalene 

Downstream Products

• 106184-48-9 N-(1-bromonaphthalen-2-yl)benzamide 
• 18271-22-2 N-(naphthalen-2-yl)benzamide 
• 122078-04-0 N¹-Methyl-N¹-phenyl-naphthalene-1,2-diamine 
• 122078-05-1 1-(2-Methylamino-phenyl)-naphthalen-2-ylamine 
• 122078-03-9 N-Methyl-N'-naphthalen-2-yl-N-phenyl-hydrazine 
• 31928-56-0 N-2-naphthyl-C-phenylnitrone 

Relevant articles and documents

Expeditious and Efficient ortho-Selective Trifluoromethane-sulfonylation of Arylhydroxylamines

A metal- and oxidant-free, practical and efficient method for the synthesis of highly versatile and synthetically useful ortho-trifluoromethanesulfonylated anilines from arylhydroxylamines and trifluoromethanesulfinic chloride was developed. This rapid tr

Direct Construction of NOBINs via Domino Arylation and Sigmatropic Rearrangement Reactions

Privileged 2-amino-2’-hydroxy-1,1’-binaphthyl (NOBIN) frameworks were constructed through a novel domino arylation of naphthylhydroxylamines with diarylhalonium salts and sigmatropic rearrangement in a transition metal-free fashion. This protocol bears broad substrate generality and proceeds under mild reaction conditions, affording diversified NOBINs in high efficiency with absolute regiocontrol during the rearrangement process. Optically active product was accessible by chiral N-heterocyclic carbene-catalyzed kinetic resolution in one pot or diastereoselective [3,3]-rearrangement guided by a removable chiral auxiliary. Remarkably, diarylchloronium and diarylbrominium salts have been employed as arylation reagents for the first time in assembling such representative biaryl frameworks.

The Cycloadditions of Nitrones with Fluoroallene

Cycloadditions of nitrones with fluoroallene proceed regiospecifically and with a remarkable stereochemical preference for addition syn to the fluorine substituent.The effects of solvent polarity on the rates and stereochemistry of these cycloadditions are reported and discussed.In general these effects are consistent with those reported for other nitrone cycloadditions, and the activation parameters are also similar.