62060-10-0Relevant articles and documents
Molybdenum catalyzed dehydration of tertiary alcohols to olefins
Kantam,Prasad,Santhi
, p. 45 - 48 (1993)
Molybdenyl (VI) acetylacetonate is shown to be an effective catalyst for easy conversion of tertiary alcohols to the corresponding olefins in high yields.
A Facile Method for Synthesis of Alkyl Phenyl Selenides. The Reaction of Diphenyl Diselenide with Oxygen-containing Compounds Using La/Me 3SiCl/cat.I2/cat.CuI System
Nishino, Toshiki,Nishiyama, Yutaka,Sonoda, Noboru
, p. 918 - 919 (2007/10/03)
Alcohols, ethers, and esters were directly converted to the corresponding alkyl phenyl selenides by the reaction of diphenyl diselenide and the La/Me 3SiCl/cat.I2/cat.CuI. It was suggested that alkyl phenyl sele
Reduction of organic halides with lanthanum metal: A novel generation method of alkyl radicals
Nishino, Toshiki,Watanabe, Toshihisa,Okada, Mitsuo,Nishiyama, Yutaka,Sonoda, Noboru
, p. 966 - 969 (2007/10/03)
Results of the reaction of alkyl halides with lanthanum metal have been shown. The reduction of alkyl iodide with 1/3 equiv of lanthanum metal efficiently proceeded to give the corresponding reductive dimerized products along with the formation of reduction and dehydroiodination products. In the case of alkyl bromides and chlorides, the reaction did not proceed under the same reaction conditions as that of alkyl iodides; however, the reaction was dramatically promoted by the addition of a catalytic amount of iodine. A reaction pathway including alkyl radicals was suggested.