63485-68-7Relevant articles and documents
REACTIONS DE WITTIG-HORNER ET DE TRANSESTERIFICATION EN UNE OPERATION PAR ACTIVATION ANIONIQUE DE LIAISONS C-H ET O-H EN MILIEU HETEROGENE CARBONATE DE POTASSIUM/ALCOOL
Mouloungui, Z.,Elmestour, R.,Delmas, M.,Gaset, A.
, p. 1219 - 1232 (2007/10/02)
The Wittig-Horner reaction carried out in various alcohols is accompanied by transesterification of the alkyl radical of the α,β-ethylenic ester formed.The occurrence of these two reactions in the same reaction medium is affected by the behavior of: i) the alcohol (solvent and reagent), ii) potassium carbonate (reagent and catalyst).The propensity for the two reactions to occur was found to depend on the polarity of the alcohol.Protic alcohols speeded both the Wittig-Horner and the subsequent transesterification reaction.Both reactions were quantitative despite the use of non-stoichiometric amounts of potassium carbonate.Regeneration in situ of the solid base observed in aprotic medium was markedly enhanced under these reaction conditions.The mechanism proposed for these two reactions incorporates this regeneration process.
BASE AND ACID DECOMPOSITION OF UNSATURATED 1-ACYL-2-TOSYLHYDRAZINES
Bellesia, Franco,Grandi, Romano,Pagnoni, Ugo M.,Trave, Roberto
, p. 511 - 514 (2007/10/02)
-
