64187-51-5

Basic information

• Product Name: Silanamine, N-[(4-methoxyphenyl)methylene]-1,1,1-trimethyl-
• CAS NO: 64187-51-5
• Molecular Formula: C11H17NOSi
• Molecular Weight: 207.348
• Mol File: 64187-51-5.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Silanamine, N-[(4-methoxyphenyl)methylene]-1,1,1-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, N-[(4-methoxyphenyl)methylene]-1,1,1-trimethyl-(64187-51-5)
• EPA Substance Registry System: Silanamine, N-[(4-methoxyphenyl)methylene]-1,1,1-trimethyl-(64187-51-5)

Safety Data

• Hazardous Substances Data: 64187-51-5(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 123-11-5 4-methoxy-benzaldehyde 
• 4039-32-1 lithium hexamethyldisilazane 
• 13892-06-3 N-trimethylsilyl(triphenylphosphoranylidene)amine 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 97974-64-6 1-(4-methoxyphenyl)but-3-en-1-amine 
• 180181-33-3 3,3-dimethyl-4-(4-methoxyphenyl)-azetidin-2-one 
• 874-90-8 4-methoxybenzonitrile 
• 1246755-21-4 N-[(4-methoxyphenyl)(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]pivalamide 
• 1351557-59-9 1-(4-methoxyphenyl)-6,7-dihydro-5H-cyclopenta[c]pyridine 
• 1133705-70-0 C₁₅H₁₂FNO₂ 
• 10374-18-2 N-[(4-methoxyphenyl)methylidene]benzamide 
• 1039746-86-5 C₁₄H₁₆N₂O 
• 180264-44-2 (+/-)-4-p-methoxy-phenyl-azetidin-2-one 
• 574743-55-8 N-[1-(4-Methoxy-phenyl)-meth-(E)-ylidene]-acetamide 
• 92-52-4 biphenyl 
• 25543-63-9 N-(3-methoxybenzylidene)-[1,1'-biphenyl]-4-amine 
• 303769-96-2 3-[(4-methoxybenzylidene)amino]benzonitrile 
• 99497-93-5 (4-methoxybenzylidene)(3-methoxyphenyl)amine 

Relevant articles and documents

Direct and practical Gilman-Speeter synthesis of 3,4-trisubstituted β-lactams via the Thorpe-Ingold effect

A highly efficient Gilman-Speeter synthesis of 3,4-trisubstituted β-lactams possessing a 4-aryl substituent is described, employing a direct, uncatalyzed Mannich reaction between TMS imines and TMS ketene acetals. The process avoids cryogenic conditions, making it more amenable to process-scale use than related methods for β-lactam synthesis. A Gilman-Speeter diastereoselective version using a sulfinyl imine and leading to homochiral sulfinyl β-aminoester is also presented.

Catalytic enantioselective one-pot aminoborylation of aldehydes: A strategy for construction of nonracemic α-amino boronates

We report a strategy for the conversion of aldehydes to enantiomerically enriched α-amino boronates through the intermediacy of in situ-generated silylimines. This transformation is brought about by Pt-catalyzed asymmetric addition of B2(pin)s

Catalytic intermolecular hetero-dehydro-diels-alder cycloadditions: Regioand diasteroselective synthesis of 5,6-dihydropyridin-2-ones

A novel catalyzed intermolecular heterodehydro-Diels-Alder reaction between push-pull 1,3-dien-5-ynes and aldimines or silylaldimines is reported. The sequence is promoted both by gold(I) or silver(I) catalysts and leads to the diastereo- and regioselective formation of 5,6- dihydropyridin-2-ones.