64298-10-8

Basic information

• Product Name: Benzene, 1-methoxy-4-methyl-2-(1-methylethenyl)-
• CAS NO: 64298-10-8
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Mol File: 64298-10-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-methyl-2-(1-methylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-methyl-2-(1-methylethenyl)-(64298-10-8)
• EPA Substance Registry System: Benzene, 1-methoxy-4-methyl-2-(1-methylethenyl)-(64298-10-8)

Safety Data

• Hazardous Substances Data: 64298-10-8(Hazardous Substances Data)

Upstream product

• 859450-18-3 2-(2-methoxy-5-methyl-phenyl)-propan-2-ol 
• 65490-14-4 2-isopropenyl-4-methylphenol 
• 77-78-1 dimethyl sulfate 
• 63113-79-1 methyl 2-methoxy-5-methylbenzoate 
• 20628-07-3 2-acetyl-4-methylanisole 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 78719-73-0 2-Hydroxy-α,α,5-trimethylbenzyl alcohol 

Downstream Products

• 62155-74-2 1-(2-methoxy-5-methyl)-phenyl propan-2-one 
• 105401-90-9 (2-isopropyl-4-methyl-phenoxy)-acetic acid 
• 31574-44-4 1-methoxy-4-methyl-2-(1-methylethyl)-benzene 
• 861547-67-3 1-iodo-2-(2-methoxy-5-methyl-phenyl)-propan-2-ol 
• 4427-56-9 Isothymol 

Relevant articles and documents

Iridium-Catalyzed C(sp3)?H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans

Intramolecular addition of an O-methyl C(sp3)?H bond across a carbon-carbon double bond occurs in the iridium-catalyzed reaction of methyl 2-(propen-2-yl)phenyl ethers. The Ir/(S)-DTBM-SEGPHOS catalyst promotes the reaction efficiently in toluene at 110–135 °C to afford 3,3-dimethyl-2,3-dihydrobenzofurans. Enantioselective C(sp3)?H addition is achieved in the reaction of methyl 2-(1-siloxyethenyl)phenyl ethers, affording enantioenriched 3-hydroxy-2,3-dihydrobenzofuran derivatives with up to 96% ee. (Figure presented.).