67583-11-3

Basic information

• Product Name: iron(II) tetraphenylporphyrin thiocarbonyl
• CAS NO: 67583-11-3
• Molecular Weight: 723.274
• Mol File: 67583-11-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: iron(II) tetraphenylporphyrin thiocarbonyl(CAS DataBase Reference)
• NIST Chemistry Reference: iron(II) tetraphenylporphyrin thiocarbonyl(67583-11-3)
• EPA Substance Registry System: iron(II) tetraphenylporphyrin thiocarbonyl(67583-11-3)

Safety Data

• Hazardous Substances Data: 67583-11-3(Hazardous Substances Data)

Upstream product

• 463-71-8 thiophosgene 
• 12582-61-5 μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron] 
• 80697-73-0 iron(II) tetraphenylporphyrin (1,2,3,6-tetrahydrothiophthalimido)chlorocarbene 
• 80697-74-1 iron(II) tetraphenylporphyrin (thiobenzyl)chlorocarbene 
• 16456-81-8 meso-tetraphenylporphyrin iron(III) chloride 
• 2976-37-6 benzyl trichloromethyl thioether 
• 5936-98-1 trichloromethyltrimethylsilane 
• 80454-62-2 Fe[TPP][CS](n-C₄H₉S)^(1-) 
• 80697-72-9 iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene 
• 67551-66-0 Fe(C₄₄H₂₈N₄)(CS)(C₂H₅OH) 

Downstream Products

• 80454-62-2 Fe[TPP][CS](n-C₄H₉S)^(1-) 
• 80697-77-4 (C(C₆H₅)C₄H₂N)4FeCS(CH₃OH) 
• 80719-03-5 (C(C₆H₅)C₄H₂N)4FeCS(P(CH₂CH₃)3) 
• 80697-78-5 (C(C₆H₅)C₄H₂N)4FeCS(NHC₄H₈O) 
• 80719-68-2 (C(C₆H₅)C₄H₂N)4Fe(CNCH₂CH₂CH₂CH₃)(NH₂CH₂CH₂CH₂CH₃) 
• 67551-66-0 Fe(C₄₄H₂₈N₄)(CS)(C₂H₅OH) 
• 67670-43-3 thiocarbonyl(5,10,15,20-tetraphenylporphyrinato)iron(II)(pyridine) 
• 16999-25-0 meso-tetraphenylporphyrinatobis(pyridine)iron(II) 
• 80719-02-4 (C(C₆H₅)C₄H₂N)4FeCS(NH₂CH(CH₃)2) 

Relevant articles and documents

FTIR and carbon-13 NMR spectra of chalcocarbonyl(5,10,15,20-tetraphenylporphinato)iron(II) complexes

The room-temperature, FTIR difference spectra of the solid chalcocarbonyl(5,10,15,20-tetraphenylporphinato)iron(II) derivatives, FeTPP(CX) and FeTPP(CX)L (X = S, Se; L = pyridine, EtOH), have been recorded (in CsI disks) in order to examine the influence of the axially bound CX and L ligands on the vibrations of the metal-porphyrin ring.The 13C NMR spectra of these complexes in CD2Cl2 have been measured at room temperature for a similar reason.The vibrations and 13C resonances of the metal-porphyrin ring are only slightly affected by the presence of the axial ligands.The positions of the 13CX NMR resonances and the ν(CX) modes in the i.r. are dependent on the nature of L.

A new route to thiocarbonyl-iron complexes: Preparation of FeII[porphyrin][C(Cl)SR] carbene complexes and their conversion to FeII[porphyrin][CS] complexes

The reaction of trichloromethyl-thioalkyl compounds including the widely used fungicides Captan and Folpet with iron(II) porphyrins in the presence of a reducing agent in excess leads to the formation of new carbene complexes, Fe[porphyrin][C(Cl)SR], whose stabilities are strongly dependent on the nature of the R substituent. Upon treatment by a catalytic amount of FeCl2 or CuCl2, some of them are decomposed into thiocarbonyliron(II)-porphyrin complexes, Fe[porphyrin][CS], in nearly quantitative yields. Various Fe[porphyrin][CS][L] complexes have thus been obtained by this method and characterized by UV-visible, IR, and 1H and 13C NMR spectroscopy. They are very stable to dioxygen and nucleophiles but react with primary amines R′NH2 in excess to give the Fe[porphyrin][CNR′][R′NH2] complexes. Reduction of C6H5SCHCl2 by iron(II) tetraphenylporphyrin, Fe[TPP], leads to the Fe[TPP][CHSC6H5] complex, which is the first example of an iron(II) porphyrin complex bearing a secondary CHR carbene.

REACTIONS DU TRICHLOROMETHYL-TRIMETHYL-SILANE AVEC DES FERROTETRA-ARYL-PORPHYRINES

Reduction of trichloromethyltrimethylsilane by ferrotetraarylporphyrins, FeII(P), in the presence of an excess of a reducing agent, leads to the formation, of 2C complexes when iron powder is used as a reducing agent or of Fe(P)(CS) complexes when sodium dithionite is used as a reducing agent.These results can be explained by the involvement of unstable α-silylcarbeneferroporphyrin complexes.