67963-68-2

Basic information

• Product Name: (4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE
• Synonyms: P-BROMOPHENOXY(T-BUTYL)DIMETHYLSILANE;AKOS 228-12;(4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE;1-BroMo-4-[[(1,1-diMethylethyl)diMethylsilyl]oxy]benzene;4-BroMophenyl tert-ButyldiMethylsilyl Ether;4-Bromophenoxy t-Butyl Dimethylsilane;1-Bromo-4-(tert-butyldimethylsiloxy)benzene
• CAS NO: 67963-68-2
• Molecular Formula: C₁₂H₁₉BrOSi
• Molecular Weight: 287.27
• Product Categories: Organic Building Blocks;Oxygen Compounds;Protected Alcohols/Phenols;Wittig Reagents
• Mol File: 67963-68-2.mol
• Article Data: 83

Chemical Properties

• Boiling Point: 137 °C25 mm Hg(lit.)
• Flash Point: 53 °F
• Appearance: Colorless/Liquid
• Density: 1.174 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0163mmHg at 25°C
• Refractive Index: n20/D 1.511(lit.)
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: (4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: (4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE(67963-68-2)
• EPA Substance Registry System: (4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE(67963-68-2)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36-37/39-60-37-23
• RIDADR: UN 1993 3/PG 2
• WGK Germany: 3
• TSCA: No
• HazardClass: 3
• Hazardous Substances Data: 67963-68-2(Hazardous Substances Data)

Usage

Chemical Properties

Colourless Oil

InChI:InChI=1/C12H19BrOSi/c1-12(2,3)15(4,5)14-11-8-6-10(13)7-9-11/h6-9H,1-5H3

Upstream product

• 106-41-2 4-bromo-phenol 
• 108613-05-4 t-butyldimethylsilyl trichloroacetate 
• 18052-27-2 tert-butyldimethyl(phenoxy)silane 
• 106-44-5 p-cresol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 288-32-4 1H-imidazole 
• 144-55-8 sodium hydrogencarbonate 
• 68-12-2 N,N-dimethyl-formamide 
• 111864-19-8 C₇H₁₆O₂Si 
• 143422-89-3 (2-methylallyl)tertiobutyl-dimethylsilane 
• 1927-95-3 4-bromophenyl acetate 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 132777-37-8 1-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-5-phenyl-pentan-1-ol 
• 132777-36-7 1-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-4-phenyl-butan-1-ol 
• 132777-13-0 1-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-3-methyl-4-phenylbutan-1-ol 
• 137995-56-3 1-benzyl-4-<2-<4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-hydroxyethyl>piperidine 
• 82861-18-5 5-(tert-Butyl-dimethyl-silanyloxy)-2-{3-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-3-hydroxy-propyl}-phenol 
• 106191-61-1 β-<4-(tert-butyldimethylsiloxy)phenyl>-β-methyleneethanamine 
• 1523-17-7 4-bromophenyl benzoate 
• 1927-95-3 4-bromophenyl acetate 
• 25244-30-8 4-(allyloxy)bromobenzene 
• 206276-08-6 4-(tert-Butyldimethylsiloxy)triallylsilylbenzene 
• 238403-27-5 4-(tert-butyldimethylsiloxy)phenyldiphenylphosphine 
• 199277-46-8 (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra(4-tert-butyldimethylsilyloxyphenyl)-1,3-dioxolane-4,5-dimethanol 
• 441351-41-3 4'-(tert-butyldimethylsilyloxy)-3,5-dimethoxybenzhydrol 
• 441351-47-9 3,4',5-tris(tert-butyldimethylsilyloxy)benzhydrol 

Relevant articles and documents

A new aza-BODIPY based NIR region colorimetric and fluorescent chemodosimeter for fluoride

The synthesis and characterization of a novel NIR region fluoride sensor, that makes use of the aza-boron-dipyrromethene (aza-BODIPY) fluorophore, is described. An arylmagnesium bromide was formed by reacting 4-bromophenol with a tert-butyldimethylsilyl p

Use of Silylated Formiates as Hydrosilane Equivalents

The present invention relates to a method for preparing organic compounds of formula (I) by reaction between a silylated formiate of formula (II) and an organic compound in the presence of a catalyst and optionally of an additive. The invention also relates to use of the method for preparing organic compounds of formula (I) for the preparation of reagents for fine chemistry and for heavy chemistry, as well as in the production of vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, and pesticides.

Green bromination method

The invention discloses a green bromination method, and belongs to the field of green organic chemistry. Under the conditions of room temperature, opening and neutrality, reaction raw materials are aromatic hydrocarbon, olefin, alkyne, tryptamine, tryptophane and derivatives thereof with different functional groups, a bromine source is MBrx (M is Fe , Fe , Ce and the like, and x is 2-3), and the unique oxidant is H2O2. Brominated alkanes, alkenes, aromatic hydrocarbons, pyrrolo-indolines and furo-indolines and derivatives thereof can be produced. The bromination reaction is carried out by using easily available and cheap reagents (such as FeBr2, CeB3 and H2O2) in the market and the solvent, and the method has the characteristics of mild reaction conditions, wide substrate application range, simple steps, easiness in operation and no need of separation, is a green, environment-friendly and safe bromination reaction method, and has a good application prospect.