688359-69-5

Basic information

• Product Name: Dispiro[1,3-dioxolane-2,1(4H)-pentalene-4,2-oxirane], hexahydro-, (2R,3aS,6aS)- (9CI)
• Synonyms: Dispiro[1,3-dioxolane-2,1(4H)-pentalene-4,2-oxirane], hexahydro-, (2R,3aS,6aS)- (9CI)
• CAS NO: 688359-69-5
• Molecular Formula: C₁₁H₁₆O₃
• Molecular Weight: 196.24294
• Product Categories: CYCLOPENTANE
• Mol File: 688359-69-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Dispiro[1,3-dioxolane-2,1(4H)-pentalene-4,2-oxirane], hexahydro-, (2R,3aS,6aS)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Dispiro[1,3-dioxolane-2,1(4H)-pentalene-4,2-oxirane], hexahydro-, (2R,3aS,6aS)- (9CI)(688359-69-5)
• EPA Substance Registry System: Dispiro[1,3-dioxolane-2,1(4H)-pentalene-4,2-oxirane], hexahydro-, (2R,3aS,6aS)- (9CI)(688359-69-5)

Safety Data

• Hazardous Substances Data: 688359-69-5(Hazardous Substances Data)

Upstream product

• 3084-53-5 trimethylsulphonium bromide 

Downstream Products

• 688359-70-8 (1S,5S,6S,1'R)-6-hydroxy-6-(1-phenylethyl-aminomethyl)-bicyclo[3.3.0]octan-2-one ethylene ketal 

Relevant articles and documents

New β-amino alcohols with a bicyclo[3.3.0]octane scaffold in an asymmetric Henry reaction

A new category of β-amino alcohols with a bicyclo[3.3.0]octane scaffold has been synthesized and used in the direct asymmetric nitroaldol reaction (Henry reaction). Up to 74% ee was obtained with the addition of nitromethane to relatively bulky aldehydes.