700868-23-1

Basic information

• Product Name: 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne
• Synonyms: 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne
• CAS NO: 700868-23-1
• Molecular Weight: 757.735
• Mol File: 700868-23-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne(CAS DataBase Reference)
• NIST Chemistry Reference: 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne(700868-23-1)
• EPA Substance Registry System: 6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne(700868-23-1)

Safety Data

• Hazardous Substances Data: 700868-23-1(Hazardous Substances Data)

Upstream product

• 700868-22-0 1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne 
• 2917-96-6 1,4-bis(methanesulfonyloxy)-2-butyne 
• 2219-66-1 1,4-dibromobut-2-yne 

Relevant articles and documents

Synthesis of nitrogen-containing 15-membered triacetylenic macrocycles. Stable complex with palladium(0)

Selective and efficient preparation of a new type of nitrogen-containing 15-membered triacetylenic macrocycles named 1,6,11-tris(arylsulfonyl)-1,6,11- triazacyclopentadeca-3,8,-13-triynes (1) (Ar1 = Ar2 = Ar3 = 4-methylphenyl, 1aaa; Ar1 = Ar2 = 4-methylphenyl, Ar3 = ferrocenyl, 1aab) has been achieved. Macrocycle 1aaa forms a very stable complex with Pd0, being the first palladium(O) complex with a macrocyclic triyne. The three triple bonds in 1aaa are responsible for the complexation. The X-ray structures of both the ligand 1aaa and its Pd0 complex are presented. Furthermore, compound 1aaa undergoes cycloisomerization into the corresponding 2,5,8-tris[(4-methlphenyl) sulfonyl]-2,5,8-triazatrindane, 11aaa, when treated with Pd(PPh 3)4 in refluxing toluene.