70367-75-8Relevant articles and documents
THE NON-CHAIN RADICALOID C-ALKYLATION OF NITRONATE ANIONS: FURTHER EVIDENCE FOR THE MECHANISM
Katritzky, Alan R.,Chen, Jen-Luan,Marson, Charles M.,Maia, Angalamaria,Kashmiri, M. Akram
, p. 101 - 108 (2007/10/02)
The effects of the variation of solvent, pyridinium leaving group, N-substituent, and nitronate nucleophile have been studied in the C-alkylation of nitronate anions.These variations and studies of the effects of inhibitors, attempted entrainment reactions, and ESR work are all in accord with our previously suggested mechanism.
NUCLEOPHILIC SUBSTITUTION IN ORGANOMERCURY HALIDES BY A FREE RADICAL CHAIN PROCESS
Russel, Glen A.,Hershberger, James,Owens, Karen
, p. 43 - 56 (2007/10/02)
Primary and secondary alkylmercury halides react with the salts of secondary nitroalkanes to afford tertiary nitroalkanes, mercury metal, and halide ion.The reaction is light initiated and is strongly inhibited by radical scavengers.Cyclized products resu