7204-16-2

Basic information

• Product Name: ETHANOL,2-[2-(2-PHENOXYETHOXY
• Synonyms: ETHANOL,2-[2-(2-PHENOXYETHOXY;2-[2-(2-Phenoxyethoxy)ethoxy]ethanol;Triethylene glycol monophenyl ether
• CAS NO: 7204-16-2
• Molecular Formula: C₁₂H₁₈O₄
• Molecular Weight: 226.27
• Mol File: 7204-16-2.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 351.9°C at 760 mmHg
• Flash Point: 166.6°C
• Appearance: /
• Density: 1.097g/cm³
• Vapor Pressure: 1.47E-05mmHg at 25°C
• Refractive Index: 1.504
• CAS DataBase Reference: ETHANOL,2-[2-(2-PHENOXYETHOXY(CAS DataBase Reference)
• NIST Chemistry Reference: ETHANOL,2-[2-(2-PHENOXYETHOXY(7204-16-2)
• EPA Substance Registry System: ETHANOL,2-[2-(2-PHENOXYETHOXY(7204-16-2)

Safety Data

• Hazardous Substances Data: 7204-16-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H18O4/c13-6-7-14-8-9-15-10-11-16-12-4-2-1-3-5-12/h1-5,13H,6-11H2

Upstream product

• 75-21-8 oxirane 
• 108-95-2 phenol 
• 139-02-6 sodium phenoxide 
• 77544-68-4 8-tosyloxy-3,6-dioxaoctanol 
• 104-68-7 2-(2-phenoxyethoxy)ethanol 
• 107-07-3 2-chloro-ethanol 
• 19249-03-7 triethylene glycol di-(p-toluenesulfonate) 
• 123824-56-6 1-bromo-6-phenyl-3,6-dioxahexane 
• 107-21-1 ethylene glycol 
• 5197-62-6 2-[2-(chloroethoxy)ethoxy]ethanol 

Downstream Products

• 128134-57-6 1-(2',4'-dinitrophenoxy)-8-phenoxy-3,6-dioxaoctane 
• 128134-56-5 1-(4'-nitrophenoxy)-8-phenoxy-3,6-dioxaoctane 
• 730960-08-4 C₁₉H₂₄O₆S 
• 128134-60-1 1-(2',4'-dinitrophenoxy)-8-(2'-nitrophenoxy)-3,6-dioxaoctane 
• 128134-61-2 1-(2',4'-dinitrophenoxy)-8-(4'-nitrophenoxy)-3,6-dioxaoctane 
• 128134-59-8 1-(2'-nitrophenoxy)-8-(4'-nitrophenoxy)-3,6-dioxaoctane 
• 83841-01-4 triethyleneglycol bis(p-nitrophenyl)ether 
• 73776-01-9 1,10-bis-(2-nitrophenyl)-1,4,7,10-tetraoxadecane 
• 333382-87-9 2-(2-(2-(2-(4-bromophenoxy)ethoxy)ethoxy)ethoxy)ethan-1-ol 
• 125808-05-1 1-bromo-4-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzene 
• 80392-33-2 1-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzene 
• 36366-93-5 2-<2-<2-(2-phenoxyethoxy)ethoxy>ethoxy>ethanol 
• 128134-55-4 1-(2'-nitrophenoxy)-8-phenoxy-3,6-dioxaoctane 
• 333382-86-8 2-(2-(2-(4-bromophenoxy)ethoxy)ethoxy)ethan-1-ol 

Relevant articles and documents

Tough, Long-Term, Water-Resistant, and Underwater Adhesion of Low-Molecular-Weight Supramolecular Adhesives

Modern functional adhesives have attracted considerable attention due to their reversible adhesion capacities and stimuli-responsive adhesion behavior. However, for modern functional adhesives, polymeric structures were highly necessary to realize adhesion behaviors. Supramolecular adhesives from low-molecular-weight monomers were rarely recognized. Compared with polymeric adhesive materials, it remains challenging for supramolecualr adhesive materials to realize tough adhesion on wet surfaces or even under water. In this study, a new supramolecular adhesive consisting of low-molecular-weight monomers was successfully designed and prepared. Strong and long-term adhesion performance was realized on various surfaces, with a maximum adhesion strength of 4.174 MPa. This supramolecular adhesive exhibits tough and stable adhesion properties in high-moisture and underwater environments (including seawater). Long-term underwater adhesion tests display the potential application of low-molecular-weight adhesive as a marine adhesive.

PROCESS FOR THE CONTINUOUS PRODUCTION OF HIGH PURITY PHENOLIC GLYCOL ETHER

Phenolic glycol ethers, e.g., ethylene glycol phenyl ether, are prepared by a continuous, nonaqueous process comprising the steps of (A) contacting under isothermal reactive conditions in a first reactor or reaction zone an alkylene oxide, e.g., ethylene oxide, with (i) a stoichiometric molar excess of a phenolic compound, e.g., phenol, and (ii) a catalytic amount of a base, e.g., sodium hydroxide, homogeneously dispersed throughout the phenolic compound, to form a first intermediate phenolic glycol ether product, (Bj transferring the first intermediate phenolic glycol ether product to a second reactor or reaction zone, and ( C) subjecting the first intermediate phenolic glycol ether product to adiabatic reactive conditions in the second reactor or reaction zone to form a second intermediate phenolic glycol ether product comprising phenolic glycol ether, unreacted phenolic compound, catalyst, water and byproduct glycols. In addition, the mono-/di-product weight ratio can be adjusted by increasing or decreasing the amount of base catalyst employed.

The Development of a New Nitrating Agent: The Unusual Regioselective Nitration of Diphenylpolyethylene Glycols and Phenylpolyethylene Glycols with Trimethylsilyl Nitrate - BF3OEt2

We have investigated the nitration of the following podands, 1-phenoxy-8-(2'-nitrophenoxy)-, 1-phenoxy-8-(4'-nitrophenoxy)-, and 1-(2',4'-dinitrophenoxy)-8-phenoxy-3,6-dioxaoctane (2, 3, and 4), and 1-(2',4'-dinitrophenoxy)-11-phenoxy-3,6,9-trioxaundecane (5), 1-phenoxy-3,6,9-trioxadecane (6), and 1-phenoxy-3,6,9,12-tetraoxatridecane (7), with trimethylsilyl nitrate catalyzed by BF3OEt2, which is soluble in nonpolar solvents.The reaction selectivity was measured by the ortho:para ratio of the nitrated products and was unusually large in CCl4.The structures of all isolated products, 1,8-bis(2'-nitrophenoxy)-, 1-(2'-nitrophenoxy)-8-(4'-nitrophenoxy)-, 1,8-bis(4'-nitrophenoxy)-, 1-(2',4'-dinitrophenoxy)-8-(2'-nitrophenoxy)-, and 1-(2',4'-dinitrophenoxy)-8-(4'-nitrophenoxy)-3,6-dioxaoctane (8, 9, 10, 11, and 12), 1-(2',4'-dinitrophenoxy)-11-(2'-nitrophenoxy)- and 1-(2',4'-dinitrophenoxy)-11-(4'-nitrophenoxy)-3,6,9-trioxaundecane (13 and 14), 1-(2'-nitrophenoxy)- and 1-(4'-nitrophenoxy)-3,6,9-trioxadecane (15 and 16), and 1-(2'-nitrophenoxy)- and 1-(4'-nitrophenoxy)-3,6,9,12-tetraoxatridecane (17 and 18), were confirmed by the independent preparation of these compounds using a modification of Joeger's method.We have invented a new nitrating system (trimethylsilyl nitrate and BF3OEt2) and have shown that the selectivity (o/p ratio of nitrated products) is unusually high in CCl4.