72863-23-1

Basic information

• Product Name: 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene
• Synonyms: 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene
• CAS NO: 72863-23-1
• Molecular Weight: 292.442
• Mol File: 72863-23-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene(72863-23-1)
• EPA Substance Registry System: 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene(72863-23-1)

Safety Data

• Hazardous Substances Data: 72863-23-1(Hazardous Substances Data)

Upstream product

• 115-95-7 linalool acetate 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 106-24-1 Geraniol 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 119306-02-4 geranyl p-toluenesulfinate 
• 119784-71-3 5-<(E)-3,7-dimethyl-2,6-octadienylthio>-1-phenyl-1H-tetrazole 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 141-12-8 neryl acetate 
• 123-35-3 7-methyl-3-methene-1,6-octadiene 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 21488-83-5 (2E)-1-phenyl-3,7-dimethyl-2,6-octadiene 
• 21488-83-5 (2Z)-1-Phenyl-3,7-dimethyl-2,6-octadiene 
• 51361-62-7 (E)-3-Benzenesulfonyl-6,10-dimethyl-undeca-5,9-dien-2-one 
• 19894-79-2 diethyl [(2E)-3,7-dimethylocta-2,6-dienyl]malonate 
• 37606-77-2 (2Z)-diethyl (3,7-dimethyl-2,6-octadienyl)malonate 
• 99372-02-8 2-(1,5-Dimethyl-1-vinyl-hex-4-enyl)-malonic acid diethyl ester 
• 31162-76-2 (cis-3,7-Dimethyl-2,6-octadienyl) phenyl sulfide 
• 35162-74-4 geranyl phenyl sulfide 
• 110109-66-5 7-chloro-3,7-dimethyl-3-(p-toluene sulfonyl)-1-octene 
• 110109-67-6 3,7-dimethyl-3-p-toluenesulfonyl-1-octene 
• 83110-46-7 3,7-dimethyl-1-(p-tolylsulfonyl)-2,6-octadiene 
• 68690-44-8 neryl p-tolyl sulfone 
• 53254-60-7 3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene 

Relevant articles and documents

Convenient synthesis of allylic sulfides and application to allylic carbon-carbon bond formation

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Palladium-Catalyzed Allylic Sulfinate-Sulfone Rearrangements

Upon treatment with a zero-valent palladium catalyst, tetrakis(triphenylphosphine)palladium, in tetrahydrofuran under mild conditions allylic p-toluenesulfinates underwent α- or γ-rearrangements of the sulfonyl group via ionic intermediates to give allylic sulfones.The regiochemistry of the rearrangements depends on the character of the intermediary allylic cationic carbons generated and the steric hindrance involved therein.Keywords - allylic sulfinate; allylic sulfone; palladium catalyst; sulfinate-sulfone rearrangement; regiochemistry; tetrakis(triphenylphosphine)palladium.

SYNTHESES A L'AIDE DE SULFONES. XXIII. SUR LA SELECTIVITE DE LA SYNTHESE DES DULFONES ALLYLIQUES

The role of the palladium ligands on the yield and regioselectivity of the reaction of conjugated dienes with arenesulphinic acids (or of allylic acetates with sodium arenesulphinates) has been investigated.Arenesulphinic acids catalyse the isomerisation of allylic sulphones.