741259-09-6Relevant articles and documents
A novel approach for introduction of C-1 oxygenated group on decalin skeleton: First asymmetric total synthesis of 1α,6α-dihydroxy- eudesm-3-ene
Zheng, Guojun,Chen, Jinchun,Fang, Lijing,Tang, Zhiyong,Li, Yulin
, p. 6177 - 6182 (2007/10/03)
This paper describes a novel approach for introduction of C-1 hydroxy on decalin ring system starting from (-)-carvone. Utilizing the substrate controlled Mukaiyama aldol reaction and alkaline cyclization as key steps, the C-1 oxygenated decalin eudesmane