74514-19-5

Basic information

• Product Name: 2,7-Octadien-1-ol, 6-chloro-3,7-dimethyl-, acetate, (E)-
• CAS NO: 74514-19-5
• Molecular Formula: C12H19ClO2
• Molecular Weight: 230.735
• Mol File: 74514-19-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,7-Octadien-1-ol, 6-chloro-3,7-dimethyl-, acetate, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,7-Octadien-1-ol, 6-chloro-3,7-dimethyl-, acetate, (E)-(74514-19-5)
• EPA Substance Registry System: 2,7-Octadien-1-ol, 6-chloro-3,7-dimethyl-, acetate, (E)-(74514-19-5)

Safety Data

• Hazardous Substances Data: 74514-19-5(Hazardous Substances Data)

Upstream product

• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 

Downstream Products

• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 130627-66-6 1-vinyl-1,3-dimethyl-4-chlorocyclohex-3-ene 
• 130627-67-7 1-vinyl-1,3-dimethyl-4-chlorocyclohex-2-ene 
• 114499-45-5 3,7-dimethyloctanyl-1-magnesium bromide 
• 133953-79-4 3,7,11,15-tetramethylhexadeca-2(E),6,10(E)-trien-1-yl acetate 
• 69842-09-7 2α-acetoxymethyl-1β,3,3-trimethylcyclohexanol 
• 6627-74-3 (+/-)-α-cyclogeraniol 

Relevant articles and documents

Rapid Oxidation Indoles into 2-Oxindoles Mediated by PIFA in Combination with n-Bu4NCl ? H2O

We report the development of a rapid approach for directly converting indoles into 2-oxindoles promoted by HOCl formed in situ from the combination of (bis(trifluoroacetoxy) iodo)benzene (PIFA) and n-Bu4NCl ? H2O. The procedure is widely functional group tolerant and provides 2-oxindoles in up to 95% yield within 5 min. The potential applications of the developed methodology are demonstrated by the gram-scale preparation of 3-methyl-2-oxindole (11 a), the one-pot two-step syntheses of spiro-oxindoles 26 a and 26 b, and the formal synthesis of (-)-folicanthine (2). (Figure presented.).