75619-30-6

Basic information

• Product Name: Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane
• Synonyms: Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane
• CAS NO: 75619-30-6
• Molecular Weight: 442.494
• Mol File: 75619-30-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane(CAS DataBase Reference)
• NIST Chemistry Reference: Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane(75619-30-6)
• EPA Substance Registry System: Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane(75619-30-6)

Safety Data

• Hazardous Substances Data: 75619-30-6(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 855-38-9 P(p-CH₃OC₆H₄)3 
• 75619-34-0 Benzyltris-(p-methoxyphenyl)phosphonium bromide 

Downstream Products

• 15325-61-8 3-methyl-1-phenyl-1-butene 
• 14374-57-3 1-methoxy-4-(pent-1-en-1-yl)benzene 
• 61866-52-2 1-butenyl-4-methoxybenzene 
• 104-46-1 anethole 
• 588-59-0 stilbene 
• 3412-44-0 1,3-diphenylpropene 

Relevant articles and documents

Untersuchungen im Wittig-System nach einem ordnenden Konzept auf der Basis alternativer Prinzipien

Our results show that the stereoselectivity of the Wittig-reaction can be controlled by the variation of substituents in accord with the ORDERING CONCEPT OF ALTERNATIV PRINCIPLES (individual pairs, known and unknown classes of alternatives).The "all-phenyl Wittig-system" having three phenyl groups on phosphorous two in ylid- and aldehyd-position was chosen as a standard for our investigations.Differentiation in ylid-position and compensation on phosphorous and aldehyd-position were observed by the comparison of "patterns".Consequently, most of the selectivity rules of Wittig-reactions can be explained by the differentiation through alternatives in the ylid-position.Inversion or conservation of the "patterns" of measured data points to the variation in structure of starting materials, reaction rates and selectivities.Amount-controls were also described in certain systems.