75697-87-9

Basic information

• Product Name: 7-(4-Chloro-benzoyl)-3-methyl-5,6-dihydro-imidazo[2,1-b]thiazol-7-ium; chloride
• CAS NO: 75697-87-9
• Molecular Weight: 315.223
• Mol File: 75697-87-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-(4-Chloro-benzoyl)-3-methyl-5,6-dihydro-imidazo[2,1-b]thiazol-7-ium; chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 7-(4-Chloro-benzoyl)-3-methyl-5,6-dihydro-imidazo[2,1-b]thiazol-7-ium; chloride(75697-87-9)
• EPA Substance Registry System: 7-(4-Chloro-benzoyl)-3-methyl-5,6-dihydro-imidazo[2,1-b]thiazol-7-ium; chloride(75697-87-9)

Safety Data

• Hazardous Substances Data: 75697-87-9(Hazardous Substances Data)

Upstream product

• 55114-48-2 3-methyl-5,6-dihydroimidazolo<2,1-b>thiazole 
• 122-01-0 4-chloro-benzoyl chloride 

Relevant articles and documents

7-Alkylation and 7-Sulphonylation of 5,6-Dihydroimidazolo-thiazoles

Reinvestigation of the alkylation of 3-phenyl-5,6-dihydroimidazolothiazole has shown that methylation occurs exclusively at the 7-position, and that the free base is readily solvolysed to a mixture of 1-methylimidazolidin-2-one, 1-methylimidazolidine-2-thione, and diphenacyl sulphide and disulphide. 3-Methyl-5,6-dihydroimidazolothiazole with methane- and arene-sulphonyl chlorides gave the corresponding 7-sulphonylthiazolium chlorides.On heating, these rearranged to 3-(2-chloroethyl)-4-methyl-3-aryl (or alkyl)sulphonylimido-2,3-dihydrothiazoles.The 7-(4-chlorophenylsulphonyl) derivative lost this substituent with aqueous base while concentrated aqueous ammonia attacked the 7a-position leading to a 3--2-imino-4-methyl-2,3-dihydrothiazole.