77903-44-7

Basic information

• Product Name: t-2-Phenyl-c-2-(trimethylsiloxy)-r-1-cyclopropancarbonsaeure-methylester
• Synonyms: t-2-Phenyl-c-2-(trimethylsiloxy)-r-1-cyclopropancarbonsaeure-methylester
• CAS NO: 77903-44-7
• Molecular Weight: 264.397
• Mol File: 77903-44-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: t-2-Phenyl-c-2-(trimethylsiloxy)-r-1-cyclopropancarbonsaeure-methylester(CAS DataBase Reference)
• NIST Chemistry Reference: t-2-Phenyl-c-2-(trimethylsiloxy)-r-1-cyclopropancarbonsaeure-methylester(77903-44-7)
• EPA Substance Registry System: t-2-Phenyl-c-2-(trimethylsiloxy)-r-1-cyclopropancarbonsaeure-methylester(77903-44-7)

Safety Data

• Hazardous Substances Data: 77903-44-7(Hazardous Substances Data)

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 6832-16-2 methyl diazoacetate 

Downstream Products

• 36057-38-2 2-methyl-4-oxo-4-phenyl-butyric acid methyl ester 
• 103620-03-7 2-(Hydroxydiphenylmethyl)-4-oxo-4-phenylbutansaeure-methylester 
• 114057-66-8 methyl 2-(1-hydroxy-1-methylethyl)-4-oxo-4-phenylbutanoate 
• 114326-48-6 methyl 2-isopropylidene-4-oxo-4-phenylbutanoate 
• 22060-64-6 5-phenyl-3-(propan-2-ylidene)furan-2(3H)-one 
• 80737-61-7 1-Methyl-c-2-phenyl-t-2-(trimethylsiloxy)-r-1-cyclopropancarbonsaeure-methylester 
• 77903-52-7 1-Methyl-c-2-phenyl-t-2-(trimethylsiloxy)-r-1-cyclopropancarbonsaeure-methylester 
• 113649-19-7 2-(Methylthio)-5-phenyl-3-thiophencarbonsaeure-methylester 
• 114326-47-5 methyl trans-1-(1-hydroxy-1-methylethyl)-2-phenyl-2-(trimethylsiloxy)cyclopropanecarboxylate 
• 80737-78-6 methyl trans-2-phenyl-1-(2-propenyl)-2-<(trimethylsilyl)oxy>cyclopropanecarboxylate 
• 113568-46-0 4,5-Dihydro-5-hydroxy-2-(methylthio)-1,5-diphenyl-1H-pyrrol-3-carbonsauere-methylester 
• 106543-48-0 4-Phenyl-4-(trimethylsiloxy)butansaeure-methylester 
• 85515-54-4 (Z)-4-Phenyl-4-trimethylsilanyloxy-but-3-enoic acid methyl ester 
• 85515-60-2 (E)-4-Phenyl-4-trimethylsilanyloxy-but-3-enoic acid methyl ester 

Relevant articles and documents

ENANTIOSELECTIVE SYNTHESIS OF SILOXYCYCLOPROPANES AND OF γ-OXOCARBOXYLATES BY ASYMMETRIC CATALYSIS

Up to 48percent enantiomeric excess have been attained by cyclopropanation of silyl enol ethers with methyl diazoacetate in the presence of optically active Cu-catalysts.Subsequent ring opening of resulting siloxycyclopropanes gives γ-oxocarboxylates with