85515-60-2Relevant articles and documents
A NOVEL REARRANGEMENT LEADING TO METHOXYCARBONYLMETHYLATED SILYL ENOL ETHERS
Reissig, Hans-Ulrich
, p. 3943 - 3946 (2007/10/02)
Methyl 2-siloxycyclopropanecarboxylates rearrange smoothly and quantitatively to the corresponding silyl enol ethers (3) by addition of a catalytical amount of iodo trimethylsilane.Scope and limitation of this novel process as well as the synthesis of the electron rich diene (10a) are described.