80263-48-5Relevant articles and documents
Heterocycles by Cycloaddition. Part 9. Bridged Heteroannulenes by Cycloaddition-Extrusion-Ring-expansion Reactions of Mesoionic Compounds with Benzocyclopropene. A Methanothiazonine, a Methanothionine, and a Methanothiecinone
Kato, Hiroshi,Toda, Shigeo,Arikawa, Yukihiko,Masuzawa, Mayumi,Hashimoto, Masafumi,et al.
, p. 2035 - 2040 (2007/10/02)
A methanothiazonine (13) was formed by cycloaddition-extrusion-ring expansion of benzocyclopropene with a mesoionic oxathiazoliumolate (12).The reaction with a dithioliumolate (14) gave the cycloadduct (15), from which a methanothionine (16) and a methano
Novel Synthesis of the Mesoionic System 1,3-Oxazolium-4-olate
Haddadin, Makhluf J.,Kattan, Asma M.,Freeman, Jeremiah P.
, p. 723 - 725 (2007/10/02)
Thermolysis or photolysis of N-phenyldibenzoylnitrone (1) produces N-benzoylphenylglyoxanilide (5) and not the previously reported oxaziridine 2.Treatment of imide 5 with triethyl phosphite produced 2,3,5-triphenyl-1,3-oxazolium-4-olate (8), a new member