81236-33-1

Basic information

• Product Name: (2-Methanesulfonyl-2-methylsulfanyl-ethyl)-benzene
• Synonyms: (2-Methanesulfonyl-2-methylsulfanyl-ethyl)-benzene
• CAS NO: 81236-33-1
• Molecular Weight: 230.352
• Mol File: 81236-33-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-Methanesulfonyl-2-methylsulfanyl-ethyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Methanesulfonyl-2-methylsulfanyl-ethyl)-benzene(81236-33-1)
• EPA Substance Registry System: (2-Methanesulfonyl-2-methylsulfanyl-ethyl)-benzene(81236-33-1)

Safety Data

• Hazardous Substances Data: 81236-33-1(Hazardous Substances Data)

Upstream product

• 20163-71-7 methyl((methylsulfonyl)methyl)sulfane 
• 100-39-0 benzyl bromide 

Downstream Products

• 103-79-7 1-phenyl-acetone 
• 81236-35-3 (2-Methanesulfinyl-2-methanesulfonyl-ethyl)-benzene 
• 81236-37-5 (2-Chloro-2-methanesulfonyl-2-methylsulfanyl-ethyl)-benzene 
• 101-41-7 benzeneacetic acid methyl ester 
• 83593-84-4 (2-Methanesulfonyl-2-methylsulfanyl-propyl)-benzene 

Relevant articles and documents

SYNTHESIS OF CARBOXYLIC ESTERS USING FORMALDEHYDE DIMETHYL DITHIOACETAL S,S-DIOXIDE

Formaldehyde dimethyl dithioacetal S,S-dioxide (1) reacted with an alkyl bromide or a 2-alkenyl bromide (8) under phase-transfer conditions using 50percent aq.NaOH to give an alkyl or 2-alkenyl derivative of 1, whereas, in the reaction with 8 in the presence of K2CO3-KI in HMPA, 1 formed a 1-alken-3-yl derivative.Transformation of these products into the corresponding carboxylic esters was also described.