829-32-3

Basic information

• Product Name: BENZENE, 1-CHLORO-4-CYCLOHEXYL-
• Synonyms: BENZENE, 1-CHLORO-4-CYCLOHEXYL-;1-Chloro-4-cyclohexylbenzene
• CAS NO: 829-32-3
• Molecular Formula: C₁₂H₁₅Cl
• Molecular Weight: 194.7005
• Mol File: 829-32-3.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 273.5°Cat760mmHg
• Flash Point: 110.6°C
• Appearance: /
• Density: 1.066g/cm³
• Vapor Pressure: 0.00957mmHg at 25°C
• Refractive Index: 1.536
• Storage Temp.: 2-8°C
• CAS DataBase Reference: BENZENE, 1-CHLORO-4-CYCLOHEXYL-(CAS DataBase Reference)
• NIST Chemistry Reference: BENZENE, 1-CHLORO-4-CYCLOHEXYL-(829-32-3)
• EPA Substance Registry System: BENZENE, 1-CHLORO-4-CYCLOHEXYL-(829-32-3)

Safety Data

• Hazardous Substances Data: 829-32-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H15Cl/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h6-10H,1-5H2

Upstream product

• 542-18-7 cyclohexyl chloride 
• 108-90-7 chlorobenzene 
• 110-83-8 cyclohexene 
• 108-93-0 cyclohexanol 
• 7664-93-9 sulfuric acid 
• 7637-07-2 boron trifluoride 
• 108-85-0 1-bromocyclohexane 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 108-94-1 cyclohexanone 
• 110-82-7 cyclohexane 
• 106-39-8 bromochlorobenzene 
• 695-12-5 vinylcyclohexane 
• 95233-37-7 trans-4-(p-chlorophenyl)cyclohexane carboxylic acid 
• 111-24-0 1,5-dibromo-pentane 

Downstream Products

• 91494-53-0 4-chloro-1-cyclohexyl-2-nitro-benzene 
• 859180-53-3 1-chloro-4-cyclohexyl-2,5-dinitro-benzene 
• 74-11-3 para-chlorobenzoic acid 
• 91802-36-7 5-Chloro-2-cyclohexylaniline 

Relevant articles and documents

Direct Hydrodecarboxylation of Aliphatic Carboxylic Acids: Metal- and Light-Free

A mild and inexpensive method for direct hydrodecarboxylation of aliphatic carboxylic acids has been developed. The reaction does not require metals, light, or catalysts, rendering the protocol operationally simple, easy to scale, and more sustainable. Crucially, no additional H atom source is required in most cases, while a broad substrate scope and functional group tolerance are observed.

Catalyst-free Decarboxylation and Decarboxylative Giese Additions of Alkyl Carboxylates through Photoactivation of Electron Donor-Acceptor Complex

We report herein a catalyst-free method to perform decarboxylative conjugated addition and hydrodecarboxylation of aliphatic N-(acyloxy)phthalimides (redox active esters, RAEs) through photoactivation of electron-donor-acceptor (EDA) complex with Hantzsch ester (HE) in N,N-dimethylacetamide (DMA) solution. The reactions present a green method to decarboxylatively construct carbon-carbon bond and to perform hydrodecarboxylation with broad substrate scope and functional group tolerance under mild blue light irradiation condition without recourse of popularly used photoredox catalysts. (Figure presented.).

Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp2) and C(sp3) Coupling of C?Br, C?OTf, and C?Cl Bonds Enabled by a Single Palladium(I) Dimer

Full control over multiple competing coupling sites would enable straightforward access to densely functionalized compound libraries. Historically, the site selection in Pd0-catalyzed functionalizations of poly(pseudo)halogenated arenes has been unpredictable, being dependent on the employed catalyst, the reaction conditions, and the substrate itself. Building on our previous report of C?Br-selective functionalization in the presence of C?OTf and C?Cl bonds, we herein complete the sequence and demonstrate the first general arylations and alkylations of C?OTf bonds (in I dimer. This allowed the realization of the first general and triply selective sequential C?C coupling (in 2D and 3D space) of C?Br followed by C?OTf and then C?Cl bonds.