83575-79-5

Basic information

• Product Name: (2-Chloro-phenyl)-dimethylamino-trimethylsilanyloxy-acetonitrile
• CAS NO: 83575-79-5
• Molecular Weight: 282.845
• Mol File: 83575-79-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-Chloro-phenyl)-dimethylamino-trimethylsilanyloxy-acetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Chloro-phenyl)-dimethylamino-trimethylsilanyloxy-acetonitrile(83575-79-5)
• EPA Substance Registry System: (2-Chloro-phenyl)-dimethylamino-trimethylsilanyloxy-acetonitrile(83575-79-5)

Safety Data

• Hazardous Substances Data: 83575-79-5(Hazardous Substances Data)

Upstream product

• 89-98-5 2-chloro-benzaldehyde 
• 66985-47-5 2-chloro-α-[(trimethylsilyl)oxy]benzeneacetonitrile 
• 83575-89-7 N,N-dimethyl-O-(diphenylphosphinyl)hydroxyl amine 

Downstream Products

• 6526-67-6 N,N-dimethyl-o-chlorobenzamide 

Relevant articles and documents

ELECTROPHILIC AMINATION OF ACYL ANION EQUIVALENTS: MILD OXIDATION OF ALDEHYDES TO AMIDES VIA O-(TRIMETHYLSILYL)ALDEHYDE CYANOHYDRIN ANIONS

The O-(trimethylsilyl)aldehyde cyanohydrin anions 4a-p(1-)*Li(1+) react with 5 to the amines 6.This electrophilic amination corresponds to a mild and specific oxidation of the aldehydes 1a-p to the amides 7a-p.