842167-70-8

Basic information

• Product Name: Benzene, 1-(2,2-dibromoethenyl)-4-fluoro-2-(methoxymethyl)-
• CAS NO: 842167-70-8
• Molecular Formula: C10H9Br2FO
• Molecular Weight: 323.987
• Mol File: 842167-70-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(2,2-dibromoethenyl)-4-fluoro-2-(methoxymethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(2,2-dibromoethenyl)-4-fluoro-2-(methoxymethyl)-(842167-70-8)
• EPA Substance Registry System: Benzene, 1-(2,2-dibromoethenyl)-4-fluoro-2-(methoxymethyl)-(842167-70-8)

Safety Data

• Hazardous Substances Data: 842167-70-8(Hazardous Substances Data)

Upstream product

• 558-13-4 carbon tetrabromide 
• 842167-68-4 4-fluoro-2-(methoxymethyl)benzaldehyde 
• 842167-67-3 1-bromo-4-fluoro-2-(methoxymethyl)benzene 
• 202865-66-5 2-bromo-5-fluorobenzyl alcohol 
• 94569-84-3 2-bromo-5-fluorobenzaldehyde 

Downstream Products

• 842167-61-7 2-(3-butenyl)-1-ethynyl-4-fluorobenzene 
• 842167-56-0 {2-[2-(3-butenyl)-4-fluorophenyl]ethynyl}trimethylsilane 
• 842167-55-9 {2-[4-fluoro-2-(methoxymethyl)phenyl]ethynyl}trimethylsilane 

Relevant articles and documents

Copper-catalyzed allylations of zirconocene intermediates generated from o-alkenyl or o-alkynylbenzyl ether derivatives and zirconocene-butene complex

(Chemical Equation Presented) o-Alkenyl or alkynyl benzylzirconocene intermediate, which was readily generated by the reaction of 2-alkoxymethyl-styrene or 2-alkoxymethyl-1-(trimethylsilylethynyl)-benzene derivative with zirconocene-butene complex (Negishi reagent, "Cp 2Zr"), reacted with allyl or propargyl halides in the presence of a catalytic amount of CuCl to give allylation or allenylation products. Conversion to Dane's diene, which is a key intermediate for estrone synthesis, was efficiently carried out by enyne olefin metathesis of the allylation products.