849937-12-8 Usage
Hexahydro-3-phenyl azecinone ring system
The compound has a six-membered azecinone ring with three additional hydrogen atoms attached to the carbon atoms, and a phenyl group (a six-membered ring with three hydrogen atoms and three substituents) attached to the carbon atom at position 3.
Silicon atom attachment
The azecinone ring system is attached to a silicon atom through an oxygen bridge, which is a common feature in organosilicon compounds.
tert-Butyldimethylsilyl group
The silicon atom is bonded to a tert-butyldimethylsilyl (TBS) group, which is a bulky and non-reactive group often used as a protecting group in organic synthesis.
(5E)-configuration
The compound has a (5E)-configuration, indicating that the double bond between carbon atoms 5 and 6 is in the same plane as the hexahydro azecinone ring system.
Organosilicon compound
The compound belongs to the class of organosilicon compounds, which are compounds containing a silicon atom bonded to a carbon atom.
Potential uses in organic synthesis and materials science
Due to its unique properties, the compound may be used as a building block or intermediate in the synthesis of more complex organic molecules. Additionally, its presence of a phenyl group may confer certain biological activities or interactions with biological systems.
Check Digit Verification of cas no
The CAS Registry Mumber 849937-12-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,4,9,9,3 and 7 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 849937-12:
(8*8)+(7*4)+(6*9)+(5*9)+(4*3)+(3*7)+(2*1)+(1*2)=228
228 % 10 = 8
So 849937-12-8 is a valid CAS Registry Number.
849937-12-8Relevant articles and documents
Synthesis of functionalised azecine and azonine derivatives via an enolate assisted aza Claisen rearrangement
Bremner, John B.,Perkins, David F.
, p. 2659 - 2665 (2007/10/03)
This paper describes the synthesis of functionalised azecine and azonine derivatives incorporating the adrenaline motif. In a key step, an enolate assisted aza Claisen rearrangement was employed to interconvert from 6- and 5-membered heterocycles to their corresponding 10- and 9-membered lactams.
