85316-19-4

Basic information

• Product Name: α-deuterio-diphenylmethyl methyl ether
• CAS NO: 85316-19-4
• Molecular Weight: 199.257
• Mol File: 85316-19-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: α-deuterio-diphenylmethyl methyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: α-deuterio-diphenylmethyl methyl ether(85316-19-4)
• EPA Substance Registry System: α-deuterio-diphenylmethyl methyl ether(85316-19-4)

Safety Data

• Hazardous Substances Data: 85316-19-4(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 17498-07-6 1-deuteriodiphenylmethanol 
• 2235-01-0 dimethoxydiphenylmethane 
• 119-61-9 benzophenone 

Downstream Products

• 85316-18-3 4,4-Diphenyl-<1,1,4-D3>butylbromid 
• 85316-24-1 4,4-Diphenyl-<1,1,4-D3>butanol 
• 85316-42-3 4,4-Diphenyl-<1,1,4-D3>butyllithium 
• 85316-23-0 4,4-Diphenyl-<4-D1>buttersaeure 
• 85316-22-9 3,3-Diphenyl-<3-D1>propylbromid 
• 85316-21-8 C₁₅H₁₅⁽²⁾HO 

Relevant articles and documents

Single and double reductive cleavage of C-O bonds of aromatic dimethyl acetals and ketals: Generation of benzylic mono- and dicarbanions

The reductive cleavage of aromatic dimethyl acetals and ketals, 1, with Li metal in THF at low temperature allows the generation of stable α-alkoxy-α-arylsubstituted carbanions, avoiding the Wittig rearrangement. Reaction of these carbanions with various electrophiles afforded the expected products 2. Further in situ reaction of compounds 2 afforded the products of reductive electrophilic disubstitution, 3.