855278-36-3

Basic information

• Product Name: Benzylamine, o-methyl--alpha--propyl- (5CI)
• Synonyms: Benzylamine, o-methyl--alpha--propyl- (5CI);1-(2-METHYLPHENYL)BUTAN-1-AMINE;(2-isobutylphenyl)methanamine
• CAS NO: 855278-36-3
• Molecular Formula: C11H17N
• Molecular Weight: 163.25938
• Mol File: 855278-36-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzylamine, o-methyl--alpha--propyl- (5CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzylamine, o-methyl--alpha--propyl- (5CI)(855278-36-3)
• EPA Substance Registry System: Benzylamine, o-methyl--alpha--propyl- (5CI)(855278-36-3)

Safety Data

• Hazardous Substances Data: 855278-36-3(Hazardous Substances Data)

Upstream product

• 875856-04-5 1-o-tolyl-butan-1-one-imine 
• 529-20-4 2-methylphenyl aldehyde 
• 741681-31-2 (2R)-2-{[(E)-(2-methylphenyl)methylidene]amino}-2-phenylacetamide 
• 698377-72-9 (2R)-2-{[(1R)-1-(2-methylphenyl)-3-butenyl]amino}-2-phenylethanamide 
• 529-19-1 2-Methylbenzonitrile 

Relevant articles and documents

Synthesis of enantiopure 1-aryl-1-butylamines and 1-aryl-3-butenylamines by diastereoselective addition of allylzinc bromide to imines derived from (R)-phenylglycine amide

The synthesis of enantiopure 1-aryl-1-butylamines via a highly diastereoselective addition of allylzinc bromide to imines derived from (R)-phenylglycine amide is reported. These are synthesised by a three-step procedure, which involves: (a) formation of the chiral imines; (b) asymmetric addition of the allylzinc reagent; (c) removal of the chiral auxiliary by means of a reductive or non-reductive method. The reductive method provides 1-aryl-1-butylamines whereas the non-reductive method preserves the double bond to afford 1-aryl-3-butenylamines. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.