87361-22-6

Basic information

• Product Name: (4-chlorophenyl)(diphenylphosphoryl)methanone
• Synonyms: (4-chlorophenyl)(diphenylphosphoryl)methanone
• CAS NO: 87361-22-6
• Molecular Weight: 340.746
• Mol File: 87361-22-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4-chlorophenyl)(diphenylphosphoryl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (4-chlorophenyl)(diphenylphosphoryl)methanone(87361-22-6)
• EPA Substance Registry System: (4-chlorophenyl)(diphenylphosphoryl)methanone(87361-22-6)

Safety Data

• Hazardous Substances Data: 87361-22-6(Hazardous Substances Data)

Upstream product

• 18872-82-7 diphenyloxophosphinyl(4-chlorophenyl)methanol 
• 4020-99-9 diphenylphosphinous acid methyl ester 
• 122-01-0 4-chloro-benzoyl chloride 
• 104-88-1 4-chlorobenzaldehyde 
• 4559-70-0 Diphenylphosphine oxide 

Downstream Products

• 1609483-70-6 1-(4-chlorophenyl)-2-methyl-4-phenylbutan-1-one 
• 87361-29-3 <4-Chlor-α-(diphenylphosphoryl)benzyl>diphenylphosphinat 

Relevant articles and documents

Cobalt-Catalyzed Markovnikov-Selective Radical Hydroacylation of Unactivated Alkenes with Acylphosphonates

Acylphosphonates having the 5,5-dimethyl-1,3,2-dioxophosphinanyl skeleton are developed as efficient intermolecular radical acylation reagents, which enable the cobalt-catalyzed Markovnikov hydroacylation of unactivated alkenes at room temperature under mild conditions. The protocol exhibits broad substrate scope and wide functional group compatibility, providing branched ketones in satisfactory yields. A mechanism involving the Co-H mediated hydrogen atom transfer and subsequent trapping of alkyl radicals by acylphosphonates is proposed.