878132-20-8Relevant articles and documents
Water sorption by ionic liquids: Evidence of a diffusion-controlled sorption process derived from the case study of [BMIm][OAc]
Spie?, Alex,Brandt, Philipp,Schmitz, Alexa,Janiak, Christoph
, (2021/11/24)
The hydrophilicity of ionic liquids (ILs) could be exploited as desiccants or in sorption-driven heat transformation, yet reports of water sorption isotherms of pure ionic liquids are still scarce. Here, water sorption studies for the six pure hydrophilic ionic liquids with 1-ethyl-3-methylimidazolium [EMIm]+ or 1-butyl-3-methylimidazolium [BMIm]+ cations and acetate [OAc]?, formate [HCOO]? or lactate [Lac]? anions show a steady and high water uptake with a small hysteresis between absorption and desorption over the relative pressure range of p/p0 = 0 – 0.9 for the first time. Repeated static volumetric sorption measurements with different amounts or different surface area of the example IL [BMIm][OAc] reveal a slow and strongly diffusion-driven sorption process stemming from the absorption of surface-adsorbed water into the bulk IL. Extrapolation of the water uptake to very small IL amounts with negligible kinetic hindrance gives an equilibrium water uptake capacity of over 2100 mg/g(IL) at p/p0 = 0.9. Gravimetric control experiments at a relative humidity of 75.5 % confirm the time-dependence with the IL surface area at the gas–liquid-interface and the amount of the IL to reach the equilibrium uptake of 1040 mg/g at p/p0 = 0.75.
Imidazolium ionic liquids: A simple anion exchange protocol
Dinares, Immaculada,Garcia De Miguel, Cristina,Ibanez, Anna,Mesquida, Neus,Alcalde, Ermitas
supporting information; experimental part, p. 1507 - 1510 (2010/06/11)
An efficient and simple protocol was developed to obtain quantitative iodide or bromide exchange for a broad range of anions in imidazolium ionic liquids. Selected anions were loaded in an anion exchange resin using two different procedures and were then used to provide a pure convenient ion pair. The Royal Society of Chemistry 2009.