89652-23-3Relevant articles and documents
Three-component reaction between isocyanides, aliphatic amines and elemental sulfur: Preparation of thioureas under mild conditions with complete atom economy
Nguyen, Thanh Binh,Ermolenko, Ludmila,Al-Mourabit, Ali
, p. 3172 - 3179 (2015/01/09)
The reaction of isocyanides with aliphatic amines in the presence of elemental sulfur was found to proceed efficiently at, or near, room temperature to produce thioureas in excellent yields and with complete atom economy.
Heterocycle formation via palladium-catalyzed intramolecular oxidative C-H bond functionalization: An efficient strategy for the synthesis of 2-aminobenzothiazoles
Joyce, Laurie L.,Batey, Robert A.
supporting information; experimental part, p. 2792 - 2795 (2009/11/30)
N-Arylthioureas are converted to 2-aminobenzothiazoles via Intramolecular C-S bond formation/C-H functionalization utilizing an unusual cocatalytic Pd(PPh3)4MnO2 system under an oxygen atmosphere at 80 °C. This method elim
Fluorous electrophilic scavengers for solution-phase parallel synthesis
Zhang, Wei,Chen, Christine Hiu-Tung,Nagashima, Tadamichi
, p. 2065 - 2068 (2007/10/03)
A fluorous isatoic anhydride and isocyanate are synthesized and used as scavengers for amines in solution-phase parallel synthesis of urea, thiourea, and β-hydroxyamine analogs. The resulting fluorous derivatives are readily separated from the reaction mi